The invention provides a heterogeneous chain extension synthesis method for waterborne
polyurethane. The method comprises the following steps: S1, pre-polymerizing: dehydrating
polyester polyol, and performing a pre-
polymerization reaction on the dehydrated
polyester polyol and diisocyanate; S2, performing hydrophilic chain extension and cross-linking: adding a hydrophilic chain
extender, a cross-linking agent and a
diluent to a material obtained in step S1, and performing a chain extension and cross-linking reaction; S3, neutralizing and extending the chain: adding neutralizing amine, water,the
diluent, a pH buffer agent and
fatty amine to a material obtained in step S2, and ending the reaction to obtain a
prepolymer; S4, performing dispersing emulsification: adding water to a material obtained in step S3 to achieve emulsification in order to uniformly disperse the
prepolymer in water; and S5, performing a post-chain extension reaction: adding a post-chain extension amine to a material obtained in step S4, performing chain extension in water, and performing reduced pressure
distillation to remove the
solvent in order to obtain the waterborne
polyurethane. The method uses
fatty amine to carry out chain extension in a heterogeneous state in order to synthesize the waterborne
polyurethane resin with high content of allophanate; and the obtained
emulsion has the advantages of small
micelle particle size, low
viscosity, good leveling property and good storage performance.