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Method for preparing catalyst used for methanol/dimethyl ether high selectivity propylene preparation

The invention provides a method for preparing a catalyst used for methanol / dimethyl ether high selectivity propylene preparation, and specifically provides a method for preparing nanometer layer structured ZSM-5 molecular sieve by employing an asymmetric gemini quaternary ammonium surfactant as a template. The method comprises specific steps as follows: (1) preparing solution A by adding the template to a mixed solution comprising water and ethanol, and preparing solution B by adding aluminum sources to sulfur solution; (2) slowly adding the B solution to the A solution, uniformly stirring the mixed solution comprising the A solution and the B solution, and then adding the aluminum sources to form initial gel; and (3) moving the gel to a crystallization kettle for crystallization under 100-200 DEG C for 1-10 days. A ZSM-5 molecular sieve prepared according to the invention is in a nanometer layer structure with the thickness being 20-100 nm, the silica-alumina ratio of the molecular sieve can be adjusted, and the specific surface area and the pore volume of the molecular sieve are quite large. In a methanol / dimethyl ether high selectivity propylene preparation reaction, the propylene selectivity and P / E ratio of the nanometer layer structured ZSM-5 molecular sieve are higher than that of a conventional ZSM-5 molecular sieve, and the service lifetime of the catalyst is longer.
Owner:巩雁军 +1
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