The invention relates to a preparation process of a flaky pure 
copper powder catalyst. The preparation process comprises the steps of: preparing 
copper cuttings, 
grinding the 
copper cuttings, and grading flaky copper to prepare the flaky pure copper 
powder catalyst. As any element harmful to an environment is not introduced to the whole process course, the harmful 
impurity content is low, and the stability of product quality is good; the catalytic characteristic is obviously better than that of common composite copper 
powder, so that the effect of synthesizing a 
metal catalytic 
system by an organosilicone 
monomer is improved, organosilicone 
monomer synthesis and the space time yield of fluidized beds are increased, the synthetic reaction period is prolonged, the preparation efficiency of dimethyldichlorosilance is improved, the cost is reduced, and the benefits are created; and promoters, such as Zn, Sn and P are used so that the synthetic reaction of the organosilicone 
monomer can be flexibly regulated according to 
impurity conditions in the fluidized beds and contact 
compositional variation, and the problems of 
low activity and selectivity of the composite copper powder and deteriorated catalytic performances as reaction goes on are solved.