The invention relates to a method for processing excimer laser irradiation, which is used for modifying textile surface, which comprises following steps: firstly, placing an object which will be processed, secondly, regulating the distance between the excimer laser irradiation and textile, thirdly, regulating the pressure strength in an excimer laser irradiation processing chamber, fourthly, processing by irradiating, and irradiating the object which will be processed for 0.1-0.5min. The method of the invention for modifying the surface of the textile is highly effective and convenient. The hydrophilicity of the textile surface which is modified is greatly increased, the appearance dying depth is also improved, and the influence for warp and weft breaking strength is not big.