The invention discloses an anhydrous carbon dioxide absorbent and a method for absorbing / desorbing carbon dioxide. A preparation method for the anhydrous carbon dioxide absorbent comprises the following steps: dissolving amine into methanol, and carrying out stirring until the amine is completely dissolved, so as to obtain a mixed solution; adding hollow silicon dioxide microspheres or porous silicon dioxide microspheres in the obtained mixed solution, continuing to carry out a reaction for 2 to 8 hours with stirring, and carrying out vacuum drying after the reaction ends up, so as to obtain amine modified silicon dioxide microspheres; and mixing the amine modified silicon dioxide microspheres with 2-[2-(dimethylamino)ethoxy]ethanol, thereby obtaining an amine modified silicon dioxide microsphere emulsion shaped anhydrous carbon dioxide absorbent, wherein the mass percent range of the amine modified silicon dioxide microspheres in the absorbent is 5wt% to 40wt%. The carbon dioxide absorption capacity of the anhydrous carbon dioxide absorbent is more than the double of the sum of absorption capacity of a pure solid adsorbent and absorption capacity of a pure liquid-phase absorbent,so that the anhydrous carbon dioxide absorbent can be applied to industries with high carbon dioxide emission such as fossil fuel power plants, cement plants, steel works and oil refineries.