The invention relates to a lead-calcium-tin-copper rare earth grid alloy, a positive grid and a lead-acid storage battery. The lead-calcium-tin-copper rare earth grid alloy comprises the following components of, in weight by percentage, 0.04wt%-0.1wt% of calcium, 0.3wt%-1.0wt% of tin, 0.02wt%-0.06wt% of copper, 0.02wt%-0.2wt% of rare earth elements and the balance lead; and the method comprises the following steps of S1, dividing the required amount of electrolytic lead in claim 1 into two components, namely a component 1 and a component 2; S2, preparing copper rare earth master alloy; and S3,preparing the lead-calcium-tin-copper rare earth grid alloy. According to the lead-calcium-tin-copper rare earth grid alloy, the positive grid and the lead-acid storage battery, lanthanum and ceriumrare earth elements and copper elements are simultaneously added on the basis of the lead-calcium alloy which is widely used at present, so that the impedance of an oxide film on the surface of the grid can be effectively reduced, the deep cycle performance is improved, the growth of lead dioxide can be promoted, the corrosion resistance of the alloy is improved, good deep cycle performance and longer floating charge service life are realized, and meanwhile, the production cost is further reduced.