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76results about How to "Low structural stability" patented technology

Metal oxide thin film transistor and manufacturing method thereof

The invention provides a metal oxide thin film transistor and a manufacturing method thereof. The metal oxide thin film transistor comprises a substrate, a gate, a gate insulating layer, a metal oxide semiconductor layer and a barrier layer hierarchically arranged on the substrate, a passivation layer arranged at the outermost layer, as well as a source and a drain connected with the metal oxide semiconductor layer respectively; a diffusion element containing insulator thin film layer adjacent to the barrier layer is arranged on the side opposite to the metal oxide semiconductor layer; and the diffusion element is any one of fluorine, nitrogen and hydrogen elements. The manufacturing method comprises the steps of arranging the diffusion element containing insulator thin film layer adjacent to the barrier layer on the side opposite to the metal oxide semiconductor layer, wherein the diffusion element is any one of fluorine, nitrogen and hydrogen elements; and diffusing the fluorine, nitrogen or hydrogen element to the metal oxide semiconductor layer of the thin film transistor via a thermal diffusion method, till reaching the metal oxide semiconductor thin film and the interface of the gate insulating layer.
Owner:SHAANXI NORMAL UNIV

Wear detection-based online detection method for rotation state and chord wear of hob of shield/TBM

The invention discloses a wear detection-based online detection method for a rotation state and chord wear of a hob of a shield/TBM. Whether the hob rotates or not, whether the hob generates chord wear or not, and a chord wear state are judged according to detected hob state signal change characteristics. The method comprises the following steps: in a normal running wear state of the hob, acquiring a signal and calibrating a time-based change curve a of the signal; fitting out a time-based change curve b of the acquired signal of the hob in an actual working condition; analyzing a change ruleof the curve b, and judging whether the hob rotates or not; performing correlation analysis on the curve a and the curve b, and judging whether the hob is in normal wear or not; and increasing a sampling frequency, fitting out a time-based change curve c of the acquired signal, and judging whether the hob generates the chord wear or not and the edge number of chord wear. On the basis of an existing wear detection device, other detection devices are not additionally arranged, and by directly analyzing the signal acquired by the wear detection device, the rotation state of the hob and whether the hob generates the chord wear or not are judged, so that the detection method is simple and reliable.
Owner:CENT SOUTH UNIV

Long-span arch bridge with single-leaf hyperboloid variable cross-section concrete-filled steel tube space truss arch rib

The invention provides a long-span arch bridge with a single-leaf hyperboloid variable cross-section concrete-filled steel tube space truss arch rib. The long-span arch bridge with the single-leaf hyperboloid variable cross-section concrete-filled steel tube space truss arch rib is characterized in that a traditional equal cross-section arched steel tube arch limb is reformed into a single-leaf hyperboloid variable cross-section arched steel tube arch limb, and a four-limb space truss arch ribs is basket-shaped. The long-span arch bridge with the single-leaf hyperboloid variable cross-sectionconcrete-filled steel tube space truss arch rib has the advantages of reducing cross-section size at the vault, increasing cross-section size at the arch foot, meeting the mechanical characteristics of an arch bridge structure of large axial force at the arch foot and small axial force at the arch top, effectively reducing the center of mass and stiffness center of the arch bridge structure, improving the stability of a super-long span concrete filled steel tube arch bridge, reducing lifting construction weight of a mid-span vault segment and effectively lowering risk difficulty of construction lifting with multiple curved conical steel tube segments welded and assembled into the single-leaf hyperboloid variable cross-section steel tube arch limb, and improving the mechanical performance of the super-long span arch bridge, and allowing a super-long-span concrete filled steel tube arch bridge with 1000-meter span to be constructed with the single-leaf hyperboloid variable cross-sectionarched steel tube arch limb to construct the four-limb space truss arch rib to further construct the concrete-filled steel tube arch bridge.
Owner:江苏交通工程咨询监理有限公司

Lignin hard carbon microsphere, hydrothermal preparation method and alkali metal ion battery negative electrode using lignin hard carbon microspheres

The invention relates to a lignin hard carbon microsphere, a hydrothermal preparation method and an alkali metal ion battery negative electrode using the lignin hard carbon microspheres. Lignin is used as a precursor, and the lignin carbon microspheres are prepared by adopting a hydrothermal method. Lignin is firstly dissolved in water under full stirring to obtain a lignin solution; hydrothermalreaction is directly carried out on the lignin solution or the hydrothermal reaction is carried out after acid and alkali are added to adjust the pH value of the solution to obtain a lignin hydrothermal microsphere precursor; and after drying, the lignin microspheres are put into a tubular furnace, and high-temperature carbonization is carried out under the protection of inert gas to obtain the lignin carbon microspheres. The lignin carbon microsphere is high in sphericity degree, less in adhesion condition, good in structural stability, good in dispersity and capable of keeping a high-dispersion state. Low-cost process synthesis of industrial waste lignin hydrothermal balling is studied, and the industrial waste lignin hydrothermal balling is successfully applied to a negative electrode material of an alkali metal ion battery and high capacity, good rate charge and discharge performance and cycling stability are shown.
Owner:TIANJIN UNIV

Method for beyond-limit arch replacing construction during preliminary bracing of large-section loess tunnel

The invention discloses a method for beyond-limit arch replacing construction during preliminary bracing of a large-section loess tunnel. The method includes the steps of firstly, conducting radial grouting reinforcement on an arch wall, wherein radial grouting reinforcement is conducted on an arch replacing required section where arch replacing is required in the constructed loess tunnel from back to front; and secondly, conducting arch replacing construction, wherein a reinforced preliminary bracing structure in the arch replacing required section is detached, and preliminary bracing construction is conducted on the arch replacing required section synchronously in the detaching process. The method is simple in step, reasonable in design, simple in construction and good in use effect; theradial grouting reinforcement is conducted on the arch wall to reinforce the arch wall of a tunnel hole first, so the structural stability of the tunnel in the arch replacing process is ensured; segmented reinforcing is conducted on the preliminary bracing structure of the tunnel through a plurality of sleeve arch units for a reinforced sleeve arch in the arch replacing required section, so detaching is convenient; and moreover, the sleeve arch units are complementary and together improve the supporting force, so the adverse effects on the structural stability of the tunnel in the detaching process of each sleeve arch unit can be effectively reduced, and the safety and reliability of the arch replacing construction process are ensured.
Owner:CHINA RAILWAY 20 BUREAU GRP

Large-section loess tunnel supporting system and supporting construction method

The invention discloses a large-section loess tunnel supporting system and a supporting construction method. The large-section loess tunnel supporting system comprises a tunnel forepoling structure, atunnel initial supporting structure and a tunnel secondary lining. The upper surface of an inverted arch secondary lining in the tunnel secondary lining is a horizontal plane, and an inverted arch backfill layer is arranged on the horizontal plane. The supporting construction method comprises the following steps of firstly digging a tunnel and conducting initial supporting; and secondly constructing the secondary lining and backfilling the inverted arch. The large-section loess tunnel supporting system is reasonable in design, easy and convenient to construct, high in construction efficiencyand good in use effect, the tunnel forepoling structure, the tunnel initial supporting structure and the tunnel secondary lining constitute a combined supporting system to stably and reliably supportthe large-section loess tunnel, the upper surface of the inverted arch of the secondary lining is adjusted to be a horizontal plane, the construction process of the inverted arch of the tunnel can beeffectively simplified, and the rigidity of the inverted arch of the tunnel is greatly improved; in this way, the construction efficiency of the tunnel secondary lining is improved, the ring sealingtime of the tunnel secondary lining is shortened, the integrity of the tunnel secondary lining is higher, and the overall force bearing effect is better.
Owner:CHINA RAILWAY 20 BUREAU GRP

Bimetal cobalt oxide-based oxide as well as preparation method and application thereof

The invention discloses a bimetal cobalt oxide-based oxide as well as a preparation method and application thereof. The general formula of the bimetal cobalt oxide-based oxide is MaCobOn, a is 0-3, bis 0-3, a and b do not include 0, n is determined by the oxidation state of other elements, M is selected from one or more of iron, nickel, manganese, zinc or copper, and the surface of the bimetal cobalt oxide-based oxide has defects. The invention also discloses a preparation method and application of the catalyst. The structure of the precursor is controlled by regulating the optimal metal ionratio of the two transition metals and changing the mixed alcohol solvent in the solvothermal reaction, and finally the MaCobOn with different active site distributions can be obtained. As an oxygen reduction catalyst, the MaCobOn has the advantages of proper defects, high activity and stable performance, and meanwhile, the introduction of M metal greatly improves the electron transfer efficiencyand realizes an efficient oxygen reduction process. The preparation process of MaCobOn is simple, the process operability is high, and MaCobOn has good application prospects in the fields of metal-airbatteries, fuel cells, electrolytic cells, super capacitors and the like.
Owner:TIANJIN UNIV OF SCI & TECH

Construction method of loess tunnel entrance section through landslide mass

The invention discloses a construction method of a loess tunnel entrance section through a landslide mass. The method comprises the following steps that 1, an entrance soil layer is pre-reinforced; 2,a tunnel entrance is constructed; 3, excavation and initial support construction is conducted on the reinforced tunnel section; 4, a reinforced tunnel section base is reinforced; 5, the reinforced tunnel section is subjected to secondary lining construction; 6, excavation and initial support construction is conducted on a rear side tunnel section; and 7, the rear side tunnel section is subjectedto secondary lining construction. The method is reasonable in design, simple and convenient to construct and good in use effect, cement-soil mixed piles are adopted for pre-reinforcement before excavation, a construction process of the tunnel entrance section through the landslide mass is guaranteed to be safe and reliable, meanwhile, the tunnel entrance section is excavated by adopting a three-step excavation method, the reinforced tunnel section base is reinforced, an excavation process of the tunnel entrance section through the landslide mass can be guaranteed to be safe and reliable, in addition, the influence on the stability of a soil layer on the circumferential side of the tunnel entrance is small, and the stability of the excavated and formed tunnel entrance can be effectively improved.
Owner:CHINA RAILWAY 20 BUREAU GRP

Through landslide body loess tunnel construction method

The invention discloses a through landslide body loess tunnel construction method. The through landslide body loess tunnel construction method comprises the following steps of constructing a tunnel entrance section and a tunnel exit section simultaneously; and respectively constructing an inclined shaft auxiliary construction inlet section and an inclined shaft auxiliary construction outlet section through a tunnel inclined shaft when the tunnel entrance section and the tunnel exit section are constructed. The through landslide body loess tunnel construction method is reasonable in design, convenient to construct and good in using effect; the loess strata in the construction area where the tunnel entrance section is positioned is subjected to reinforcement treatment by using a cement soilmixing pile in advance before excavation, and the reinforcement length and the reinforcement depth are effectively limited; a loose soil body on a hole body of a tunnel hole is solidified in advance so as to ensure the safety and reliability of the construction process of a hole inlet section of the through landslide body loess tunnel; meanwhile, in the construction process of the tunnel by adopting a three-step excavation method, the construction process of track plates is completed synchronously, so that the construction process of the loess tunnel can be completed easily, conveniently and quickly; and the stability of an excavated and formed tunnel hole can be effectively improved.
Owner:CHINA RAILWAY 20 BUREAU GRP

Positive electrode material and preparation method thereof, and secondary battery

The invention provides a positive electrode material and a preparation method therefor, and a secondary battery.The positive electrode material comprises a core material having a layered structure andlithium nickel manganese oxide having a spinel structure and coating the core material, D50 of the lithium nickel manganese oxide is 30-100 nm and a specific surface area BET is 20-100 m<2> / g. According to the positive electrode material, the overcharge potential safety hazard of the secondary battery can be reduced from a chemical system, and meanwhile, a first discharge capacity and a capacityretention ratio of the secondary battery can be improved so that the cycle performance of the secondary battery is improved. The preparation method of the positive electrode material comprises the following steps: (1) preparing lithium nickel manganese oxide, namely preparing a lithium nickel manganese oxide powder material with a spinel structure and a D50 of 30-100nm by adopting a liquid-phase sol-gel method; and (2) coating the lithium nickel manganese oxide: coating the core material with the layered structure of the lithium nickel manganese oxide by using a dry coating method. The lithiumnickel manganese oxide powder shell material is prepared by adopting a liquid-phase sol-gel method, and the coating layer is prepared by adopting a dry method so that the prepared material is betterin coating performance, and better overcharge secondary battery safety can be obtained.
Owner:SHENZHEN POLYTECHNIC

Deep-buried loess tunnel deformation control construction structure based on cover arch and method

The invention discloses a deep-buried loess tunnel deformation control construction structure based on a cover arch and a method. The structure comprises a tunnel primary support structure body for primary support of a tunnel and the reinforcement cover arch arranged on the inner side of the tunnel primary support structure body, wherein the tunnel primary support structure body and the reinforcement cover arch form a reinforced primary support structure body. The method comprises the following steps of 1, carrying out tunnel excavation and primary support; and 2, carrying out reinforcement arc arch construction. The structure and the method have the advantages of being reasonable in design, simple and convenient in construction and good in use effect, the reinforcement cover arch is adopted to reinforce the tunnel primary support structure body and form the reinforced primary support structure body, an isolation layer is arranged between the reinforcement arc arch and the tunnel primary support structure body, in addition, the reinforcement cover arch adopts a plurality of cover arch units to reinforce the tunnel primary support structure body in a segmented mode, so that the construction is simple and convenient, moreover, the reinforced primary support structure body formed by construction has certain self-adaptive capacity and can effectively adapt to the deformation condition of soil mass on the peripheral side of the tunnel, and therefore the deformation resistance of the reinforced primary support structure body can be effectively enhanced.
Owner:CHINA RAILWAY 20 BUREAU GRP
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