The invention discloses a bipolar membrane based on a pre-modified
metal organic framework material and a preparation method thereof. A commercial anion exchange membrane is used as a substrate, the surface of the anion exchange membrane is coated with an
adhesive, a
metal organic framework material and sulfonated polyethersulfone are blended and coated on an
adhesive layer, and the bipolar membrane is prepared through a
solvent evaporation method. By introducing the pre-modified
metal organic framework material, the problems that the nano material is easy to
agglomerate, the
doping amount istoo low, the nano material is easy to leak and the like are better solved, the structure of the membrane is improved, an effective channel is provided for migration of ions in the cation exchange membrane side, the
ion migration rate can be increased, the
succinic acid yield is increased. The bipolar membrane has the advantages of stable membrane performance, simple preparation process, high separation efficiency, high
doping amount and the like, and solves the problem that a
cathode membrane and an
anode membrane in the bipolar membrane are easy to layer and peel. The bipolar membrane has a wide application prospect in the field of preparation of
succinic acid from the bipolar membrane.