The invention discloses a
reaction system for preparing
stress whitening resistant
polypropylene and a method for preparing
polypropylene by employing the
system. A liquid-phase stirring reactor is sequentially connected with a gas-phase
fluidized bed flashing reactor and at least two gas-phase
fluidized bed reactors which are connected in series. According to the method,
polypropylene granules are sequentially subjected to propylene liquid-phase homopolymerization, propylene gas-phase homopolymerization, propylene
ethylene gas-phase copolymerization and
ethylene gas-phase spontaneous
polymerization through the
reaction system and a Ziegler-
Natta catalytic
system, and pass a gas-
solid drying and separating
system and are discharged, so that the
stress whitening resistant polypropylene is obtained. The system has the advantages that a copolymerization reactor is additionally arranged at the stage of gas-phase
polymerization, a flow of propylene liquid-phase homopolymerization, propylene gas-phase homopolymerization, propylene
ethylene gas-phase copolymerization and ethylene gas-phase spontaneous
polymerization is formed, a notable characteristic is reflected in the stage of gas-phase polymerization,
polymer granules are subjected to three polymerization stages including propylene homopolymerization, propylene ethylene copolymerization and ethylene spontaneous polymerization, and the interface integration of different structural molecules is properly improved, so that the
stress whitening resistant polypropylene has relatively good
mechanical property and
processing property, and the
reaction system further has outstanding characteristics that the
occurrence probability of stress
cracking is reduced, and the stress whitening phenomenon of products is obviously improved.