A resilient container configured to receive a quantity of hyperpolarized
noble gas includes a wall with at least two
layers, a first layer with a surface which minimizes spin-relaxation and a first or second layer which is substantially impermeable to
oxygen. The container is especially suitable for collecting and transporting 3He. The resilient container can be configured to directly deliver the hyperpolarized
noble gas to a target interface by deflating or collapsing the inflated resilient container. Related collection and transporting methods include forming the wall of the container and collecting the hyperpolarized gas in a way which minimizes its
exposure to de-polarizing impurities. Also, a container includes a quantity of polarized gas and extends the T1 life by configuring the wall of the container with a controlled thickness of the
surface coating and overlays the interior with an exterior which is substantially impermeable to
oxygen. In addition, an O-ring and seal is configured to minimize the depolarizing effect of the collection device. Also disclosed is a method for determining the gas
solubility in an unknown
polymer or liquid using the measured relaxation time of a hyperpolarized gas.