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40results about How to "Improve acid properties" patented technology

ZSM-5/ZSM-12 composite molecular sieve and synthetic method thereof

The invention provides a ZSM-5 / ZSM-12 composite molecular sieve. The ZSM-5 / ZSM-12 composite molecular sieve has the following two crystal forms at the same time: a ZSM-12 molecular sieve and a ZSM-5 molecular sieve. The synthetic method for the ZSM-5 / ZSM-12 composite molecular sieve provided by the invention comprises the following steps: adding the ZSM-12 molecular sieve into a glucose solution for ultrasonic treatment and carrying out filtering, drying and roasting so as to obtain a treated ZSM-12 molecular sieve; then mixing water, an alkali source, a template agent, an aluminum source and a silicon source and carrying out crystallization so as to prepare pre-crystallized colloid; then mixing the pre-crystallized colloid with the treated ZSM-12 molecular sieve and carrying out crystallization at a temperature of 160 to 220 DEG C for 5 to 25 h so as to obtain the ZSM-5 / ZSM-12 composite molecular sieve. According to the invention, glucose is introduced into the pores of the ZSM-12 molecular sieve and becomes carbon after roasting; the carbon occupies the pore channels of the ZSM-12 molecular sieve to prevent alkali from entering the interior of ZSM-12 molecular sieve crystals, so the ZSM-12 molecular sieve is not destroyed in the process of crystallization and the integrity of crystal structure is maintained, which are beneficial for improvement of the physical and chemical properties and the catalytic activity of the ZSM-5 / ZSM-12 composite molecular sieve.
Owner:CHINA PETROLEUM & CHEM CORP +1

Copper-containing molecular sieve Cu-CHA, catalyst and use thereof

The present application discloses a copper-containing molecular sieve Cu-CHA, a catalyst thereof and use thereof in the treatment of diesel vehicle exhaust gas, and belongs to the field of catalytic materials. The copper-containing molecular sieve Cu-CHA consists of zeolite having a CHA framework structure and containing silicon and aluminum elements as well as 1.65-3.05wt% of Cu; the Cu-CHA molecular sieve also comprises 0.5-1.5wt% of boron, and the Cu-CHA molecular sieve has an acid content of 0.25-0.98mmol/g. The Cu-CHA molecular sieve of the present application has an acid density as highas 0.25-0.98mol/g and a Cu content as low as 1.65-3.05wt%. As a catalyst for the selective catalytic reduction of ammonia, the Cu-CHA molecular sieve has excellent storage capacity for NH3 and good low-temperature activity, and the absence of CuOx species in the high-temperature section prevents the reduction of high-temperature activity due to non-selective oxidation of NH3. The Cu-CHA molecularsieve catalyst shows excellent catalytic activity in a wide temperature window, taking into account both low temperature and high temperature activities, and still shows good catalytic activity afterbeing subjected to hydrothermal aging treatment; and after being used in the treatment of diesel vehicle exhaust, the Cu-CHA molecular sieve catalyst has significant performance advantages.
Owner:SHANDONG SINOCERA FUNCTIONAL MATERIAL CO LTD

SAPO-34/EU-1 composite molecular sieve and synthetic method thereof

The invention provides an SAPO-34/EU-1 composite molecular sieve. The SAPO-34/EU-1 composite molecular sieve has the following two crystal forms at the same time: an EU-1 molecular sieve and an SAPO-34 molecular sieve. The synthetic method for the SAPO-34/EU-1 composite molecular sieve provided by the invention comprises the following steps: adding the EU-1 molecular sieve into a glucose solution for ultrasonic treatment and carrying out filtering, drying and roasting so as to obtain a treated EU-1 molecular sieve; then mixing water, an alkali source, a template agent, an aluminum source and a silicon source with the treated EU-1 molecular sieve; and carrying out crystallization at a temperature of 150 to 240 DEG C for 15 to 100 h so as to obtain the SAPO-34/EU-1 composite molecular sieve. According to the invention, glucose is introduced into the pores of the EU-1 molecular sieve and becomes carbon after roasting; the carbon occupies the pore channels of the EU-1 molecular sieve to prevent alkali from entering the interior of EU-1 molecular sieve crystals, so the EU-1 molecular sieve is not destroyed in the process of crystallization and the integrity of crystal structure is maintained, which are beneficial for improvement of the physical and chemical properties and the catalytic activity of the SAPO-34/EU-1 composite molecular sieve.
Owner:CHINA PETROLEUM & CHEM CORP +1

Bamboo salt tea cola

The invention relates to a bamboo salt tea flavor cola which can overcome the defects of the current cola, tea drinks, sweet milk beverage and fresh water drinks. The bamboo salt tea flavor cola is produced by mixing distilled water, tea (green tea and red tea), mixed sirup, citric acid, edible flavor and vitamin C which are composed of the base materials of drinking tea, the seasoning accessories with the function of bamboo salt which mixes with aerated water, burnt sugar color, orthophosphoric acid and bamboo salt are added again. The bamboo salt tea flavor cola can completely clean and purify the cavity and the esophagus of people and has the effects of protecting and purifying cavity, eliminating and preventing cavitary diseases and has the functions of antibacterium, sterilizing and treating inflammation and has remarkable permanent curative effect. The bamboo salt tea flavor cola also has strong comprehensive effects of detoxification and toxicant elimination; as the bamboo salt tea flavor cola can balance and adjust acidity and alkalinity, the bamboo salt tea flavor cola is suitable for modern people and people of various physique to drink and has good efficacy of refreshing, quenching, cleaning cavity, eliminating inflammation, being fresh, promoting the production of body fluid, cleaning throat and clearing and nourishing intestines and stomach, thus being extremely beneficial to the health of people from head to foot and having no any side effect on human bodies.
Owner:万金林

Beta and EU-1 composite molecular sieve and synthesis method thereof

The invention provides a Beta / EU-1 composite molecular sieve which has two crystal forms of an EU-1 molecular sieve and a Beta molecular sieve at a same time. According to a Beta / EU-1 composite molecular sieve synthesis method provided by the invention, the EU-1 molecular sieve is added into a glucose solution and is subjected to an ultrasonic treatment; filtering, drying and roasting are carried out, such that a treated EU-1 molecular sieve is obtained; distilled water, an alkali source, a templating agent, an aluminum source, a silicon source and the treated EU-1 molecular sieve are mixed; and the mixture is crystallized for 25-100h under a temperature of 100-180 DEG C, such that the Beta / EU-1 composite molecular sieve is obtained. According to the invention, glucose is introduced into the micropore channels of the EU-1 molecular sieve, and is converted into carbon through roasting, such that the channels of the EU-1 molecular sieve are occupied, and alkali is prevented from entering the crystals of the EU-1 molecular sieve. Therefore, the EU-1 molecular sieve is prevented from being damaged during the crystallization reaction process, and crystal structure integrity is maintained. Therefore, the physical and chemical properties and the catalytic activity of the Beta / EU-1 composite molecular sieve can be improved.
Owner:CHINA PETROLEUM & CHEM CORP +1

Beta-Y composite molecular sieve and synthetic method thereof

The invention provides a Beta-Y composite molecular sieve. The Beta-Y composite molecular sieve has the following two crystal forms at the same time: a Y type molecular sieve and a Beta molecular sieve. The invention also provides a synthetic method for the Beta-Y composite molecule sieve. The synthetic method comprises the following steps: (1) preparing a Y structure-directing agent; (2) adding the Beta molecular sieve into a glucose solution for pretreatment; (3) mixing a silicon source, an aluminum source, inorganic base and water and adding the Y structure-directing agent; and (4) adding the treated Beta molecular sieve under stirring, carrying out crystallization and then carrying out separating, washing, drying and roasting so as to obtain the Beta-Y composite molecular sieve. According to the invention, glucose is introduced into the micro pore channels of the Beta molecular sieve and becomes carbon after roasting; the carbon occupies the pore channels of the Beta molecular sieve to prevent alkali from entering the interior of Beta molecular sieve crystals, so the Beta molecular sieve is not destroyed in the process of crystallization and the integrity of crystal structure is maintained, which are beneficial for improvement of the physical and chemical properties and the catalytic activity of the Beta-Y composite molecular sieve.
Owner:CHINA PETROLEUM & CHEM CORP +1

A kind of zsm-5 and zsm-12 composite molecular sieve and its synthetic method

The invention provides a ZSM-5 / ZSM-12 composite molecular sieve. The ZSM-5 / ZSM-12 composite molecular sieve has the following two crystal forms at the same time: a ZSM-12 molecular sieve and a ZSM-5 molecular sieve. The synthetic method for the ZSM-5 / ZSM-12 composite molecular sieve provided by the invention comprises the following steps: adding the ZSM-12 molecular sieve into a glucose solution for ultrasonic treatment and carrying out filtering, drying and roasting so as to obtain a treated ZSM-12 molecular sieve; then mixing water, an alkali source, a template agent, an aluminum source and a silicon source and carrying out crystallization so as to prepare pre-crystallized colloid; then mixing the pre-crystallized colloid with the treated ZSM-12 molecular sieve and carrying out crystallization at a temperature of 160 to 220 DEG C for 5 to 25 h so as to obtain the ZSM-5 / ZSM-12 composite molecular sieve. According to the invention, glucose is introduced into the pores of the ZSM-12 molecular sieve and becomes carbon after roasting; the carbon occupies the pore channels of the ZSM-12 molecular sieve to prevent alkali from entering the interior of ZSM-12 molecular sieve crystals, so the ZSM-12 molecular sieve is not destroyed in the process of crystallization and the integrity of crystal structure is maintained, which are beneficial for improvement of the physical and chemical properties and the catalytic activity of the ZSM-5 / ZSM-12 composite molecular sieve.
Owner:CHINA PETROLEUM & CHEM CORP +1

A kind of heavy aromatics conversion catalyst and preparation method thereof

The invention discloses a heavy aromatic conversion catalyst. The heavy aromatic conversion catalyst comprises small-particle hydrogen mordenite in a two-dimensional sheet state, the size of the small-particle hydrogen mordenite in the long-dimensional direction is 200-1000 nm, the sheet thickness of the small-particle hydrogen mordenite in the short-dimensional direction is 5-60 nm, the pyridineabsorption infrared total acid of the small-particle hydrogen mordenite is 0.5-1.35 mmol / g, and the B acid distribution of the small-particle hydrogen mordenite is 45-70%. The preparation method of the heavy aromatic conversion catalyst comprises (1) uniformly mixing a silicon source, an alkali source, N-methylpiperidine and water, performing hydro-thermal treatment on the mixed materials in a sealed state, cooling the materials down to room temperature, and then uniformly mixing an aluminum source into the hydro-thermal-treated materials; (2) aging, crystallizing, washing, drying and baking the materials obtained in the step (1), fully soaking the baked powder in an organic acid-inorganic ammonium salt aqueous solution, and performing drying, baking and forming process to obtain the heavyaromatic conversion catalyst. The heavy aromatic conversion catalyst is high in heavy aromatic conversion ability and BTX (benzene-toluene-xylene) yield.
Owner:CHINA PETROLEUM & CHEM CORP +1

A kind of beta and zsm-12 composite molecular sieve and its synthetic method

The invention provides a Beta / ZSM-12 composite molecular sieve. The Beta / ZSM-12 composite molecular sieve has the following two crystal forms at the same time: a ZSM-12 molecular sieve and a Beta molecular sieve. The synthesis method for the Beta / ZSM-12 composite molecular sieve provided by the invention comprises the following steps: adding the ZSM-12 molecular sieve into a glucose solution for pretreatment so as to obtain a treated ZSM-12 molecular sieve; then mixing water, an alkali source, a template agent, an aluminum source and a silicon source and carrying out high-temperature crystallization so as to prepare pre-crystallized colloid; then mixing the pre-crystallized colloid with the treated ZSM-12 molecular sieve and carrying out crystallization at a temperature of 100 to 180 DEG C for 5 to 25 h so as to obtain the Beta / ZSM-12 composite molecular sieve. According to the invention, glucose is introduced into the pores of the ZSM-12 molecular sieve and becomes carbon after roasting; the carbon occupies the pore channels of the ZSM-12 molecular sieve to prevent alkali from entering the interior of ZSM-12 molecular sieve crystals, so the ZSM-12 molecular sieve is not destroyed in the process of crystallization and the integrity of crystal structure is maintained, which are beneficial for improving the physical and chemical properties and the catalytic activity of the Beta / ZSM-12 composite molecular sieve.
Owner:CHINA PETROLEUM & CHEM CORP +1

A kind of modification method of ets-10 titanium silicon molecular sieve

The invention relates to an ETS-10 titanium silicalite molecular sieve modification method. The ETS-10 titanium silicalite molecular sieve modification method provided by the invention comprises the following steps: alkali treatment modification: carrying out alkali treatment modification of EST-10 titanium silicalite molecular sieve raw powder through adopting an alkaline solution, filtering, washing, and drying to obtain alkali treatment modified ETS-10 titanium silicalite molecular sieve; and realuminated modification treatment: carrying out realuminated modification treatment of the alkali treatment modified ETS-10 titanium silicalite molecular sieve through adopting an aluminum salt solution or an aluminate solution, filtering, washing, drying, and roasting to obtain the alkali treatment modification and realuminated modification treated ETS-10 titanium silicalite molecular sieve. The modification method provided by the invention adopts the alkali treatment modification and the realuminated modification treatment of the EST-10 titanium silicalite molecular sieve raw powder to be carried out, so the surface phase of the EST-10 titanium silicalite molecular sieve is rich in titanium and aluminum, abundant meso-structures are introduced, and the skeletal acidity is improved.
Owner:PETROCHINA CO LTD +1

Heavy aromatic conversion catalyst and preparation method thereof

The invention discloses a heavy aromatic conversion catalyst. The heavy aromatic conversion catalyst comprises small-particle hydrogen mordenite in a two-dimensional sheet state, the size of the small-particle hydrogen mordenite in the long-dimensional direction is 200-1000 nm, the sheet thickness of the small-particle hydrogen mordenite in the short-dimensional direction is 5-60 nm, the pyridineabsorption infrared total acid of the small-particle hydrogen mordenite is 0.5-1.35 mmol/g, and the B acid distribution of the small-particle hydrogen mordenite is 45-70%. The preparation method of the heavy aromatic conversion catalyst comprises (1) uniformly mixing a silicon source, an alkali source, N-methylpiperidine and water, performing hydro-thermal treatment on the mixed materials in a sealed state, cooling the materials down to room temperature, and then uniformly mixing an aluminum source into the hydro-thermal-treated materials; (2) aging, crystallizing, washing, drying and baking the materials obtained in the step (1), fully soaking the baked powder in an organic acid-inorganic ammonium salt aqueous solution, and performing drying, baking and forming process to obtain the heavyaromatic conversion catalyst. The heavy aromatic conversion catalyst is high in heavy aromatic conversion ability and BTX (benzene-toluene-xylene) yield.
Owner:CHINA PETROLEUM & CHEM CORP +1

A kind of beta-y compound molecular sieve and synthetic method thereof

The invention provides a Beta-Y composite molecular sieve. The Beta-Y composite molecular sieve has the following two crystal forms at the same time: a Y type molecular sieve and a Beta molecular sieve. The invention also provides a synthetic method for the Beta-Y composite molecule sieve. The synthetic method comprises the following steps: (1) preparing a Y structure-directing agent; (2) adding the Beta molecular sieve into a glucose solution for pretreatment; (3) mixing a silicon source, an aluminum source, inorganic base and water and adding the Y structure-directing agent; and (4) adding the treated Beta molecular sieve under stirring, carrying out crystallization and then carrying out separating, washing, drying and roasting so as to obtain the Beta-Y composite molecular sieve. According to the invention, glucose is introduced into the micro pore channels of the Beta molecular sieve and becomes carbon after roasting; the carbon occupies the pore channels of the Beta molecular sieve to prevent alkali from entering the interior of Beta molecular sieve crystals, so the Beta molecular sieve is not destroyed in the process of crystallization and the integrity of crystal structure is maintained, which are beneficial for improvement of the physical and chemical properties and the catalytic activity of the Beta-Y composite molecular sieve.
Owner:CHINA PETROLEUM & CHEM CORP +1

A kind of sapo-34 and eu-1 composite molecular sieve and its synthetic method

The invention provides an SAPO-34 / EU-1 composite molecular sieve. The SAPO-34 / EU-1 composite molecular sieve has the following two crystal forms at the same time: an EU-1 molecular sieve and an SAPO-34 molecular sieve. The synthetic method for the SAPO-34 / EU-1 composite molecular sieve provided by the invention comprises the following steps: adding the EU-1 molecular sieve into a glucose solution for ultrasonic treatment and carrying out filtering, drying and roasting so as to obtain a treated EU-1 molecular sieve; then mixing water, an alkali source, a template agent, an aluminum source and a silicon source with the treated EU-1 molecular sieve; and carrying out crystallization at a temperature of 150 to 240 DEG C for 15 to 100 h so as to obtain the SAPO-34 / EU-1 composite molecular sieve. According to the invention, glucose is introduced into the pores of the EU-1 molecular sieve and becomes carbon after roasting; the carbon occupies the pore channels of the EU-1 molecular sieve to prevent alkali from entering the interior of EU-1 molecular sieve crystals, so the EU-1 molecular sieve is not destroyed in the process of crystallization and the integrity of crystal structure is maintained, which are beneficial for improvement of the physical and chemical properties and the catalytic activity of the SAPO-34 / EU-1 composite molecular sieve.
Owner:CHINA PETROLEUM & CHEM CORP +1

A kind of y and zsm-35 composite molecular sieve and its synthesis method

The invention provides a Y / ZSM-35 composite molecular sieve with two crystal forms of a Y type molecular sieve and a ZSM-35 molecular sieve. The invention also provides a synthesizing method of the Y / ZSM-35 composite molecular sieve. The method comprises the following steps: (1) a Y structure-directing agent is prepared; (2) a ZSM-35 molecular sieve is added into a glucose solution and is subjected to pretreatment; (3) a silicon source, an aluminum source, an alkali source, water, the Y structure-directing agent and the treated ZSM-35 molecular sieve are mixed; and crystallization is carried out, such that the Y / ZSM-35 composite molecular sieve is obtained. According to the invention, glucose is introduced into micro-pore channels of the ZSM-35 molecular sieve, and is converted into carbon through roasting, such that the channels of the ZSM-35 molecular sieve are occupied, and alkali is prevented from entering the crystals of the ZSM-35 molecular sieve. Therefore, the ZSM-35 molecular sieve is not damaged during the crystallization reaction process, crystal structure integrity is maintained, and the physical and chemical properties and the catalytic activity of the Y / ZSM-35 composite molecular sieve can be improved.
Owner:CHINA PETROLEUM & CHEM CORP +1
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