The present invention proposes a drying system, an air conditioner and a working mode switching method, wherein the drying system includes: an outdoor heat exchanger, a first indoor heat exchanger, a second indoor heat exchanger and a compressor ;Three-way solenoid valve, the three-way solenoid valve has three ports of the first end, the second end and the third end, wherein, the first end is connected to the compressor through the four-way valve, and the second end is connected to the outdoor heat exchanger, The third end is connected to the first indoor heat exchanger; the controller, connected to the three-way solenoid valve, is used to switch between the three ports according to the received mode adjustment command, so as to adjust the working mode of the air conditioner, wherein , The working modes include preheating mode, temperature control mode and drying and dehumidification mode. Through the above technical solution, it replaces the solution of air preheating by electric heating in the related art, saves energy consumption, realizes the automatic control of heat pump drying, and can greatly save energy and reduce emission.