The invention discloses paint with strong adhesion for cooling the surface for an LED (light emitting diode) radiator. The paint is characterized by being prepared from the following components in parts by weight: 10-25 parts of inorganic colloidal particles, 1-3 parts of carbon nano-tube, 25-90 parts of electron transited spinel, 0.05-1.5 parts of rare earth oxide, 0.1-0.5 part of a stabilizing agent, 3-15 parts of epoxy resin, 2-10 parts of methyl methacrylate, 10-25 parts of nano- diatomite and 2-10 parts of ethylene glycol. The paint has remarkable heat dissipating and cooling effects, is not influenced by peripheral media, can be used in a vacuum environment, plays a role in radiating and cooling, and has the advantages of good self-cleaning performance, corrosion resistance, water resistance, flame retardance, insulating performance and acid-alkali resistance, and is convenient to construct.