The present invention provides a secondary battery which is less expensive, whose safety is extremely high, which is of
large capacity as well as good cyclic characteristic, and which uses an
aqueous solution for the electrolytic solution. A
lithium secondary battery according to the present invention is constituted by including a positive
electrode, formed by binding a positive-
electrode raw-material mixture including a positive
electrode active material, a negative electrode, formed by binding a negative-electrode raw-material mixture including a negative electrode active material, and an electrolytic solution, comprising an
aqueous solution in which a
lithium salt is dissolved, said positive electrode active material including at least one of a
layered structure lithium-
manganese composite oxide whose basic composition is LiMnO2 and an
olivine structure lithium-iron composite
phosphorus oxide whose basic composition is LiFePO4. The present lithium secondary battery can be used in the fields of communication appliances and information-related appliances, and as an electric source for electric automobiles and the like.