The invention relates to the technical field of sheets, in particular to an anti-static two-sided gold-stamped, printed and embossed PVC (polyvinyl chloride) sheet and a preparation method thereof. The sheet comprises raw materials in parts by weight as follows: 80-120 parts of PVC resin, 32-52 parts of a plasticizer, 6-10 parts of a lubricant, 1-4 parts of a heat stabilizer, 0.03-0.07 parts of a slipping agent, 0.03-0.07 parts of pigment powder and 0.1-0.5 parts of calcium powder, wherein the calcium powder is a mixture of nano calcium carbonate and heavy calcium carbonate in the weight ratio of 1:(1.5-2.5), the particle size of the nano calcium carbonate is in a range of 120-150 nm, and the particle size of the heavy calcium carbonate is in a range of 1-10 [mu]m. The raw materials are adopted, and the weight ratio of the raw materials is strictly controlled, so that the sheet is good in anti-static effect, heat-resistant, cold-resistant, acid-resistant, alkali-resistant, heavy-load-resistant, anti-aging, smooth in surface, free of cracks and bubbles, uniform in color, strong in stereoscopic impression, soft in texture, comfortable, healthy and environment-friendly.