The application relates to a kind of
etching method for regulating porous
cement-based diaphragm and its preparation method and application, and belongs to the technical field of battery diaphragm.The preparation method flow of the
cement-based diaphragm includes
cement neat paste test piece forming,
polishing,
etching and
drying.The
etching is to dissolve the composition of cement neat paste itself by using acid solution, improve the
porosity and pore
connectivity of cement neat paste, expand the
transmission channel of ions, and then improve the
ion conductivity of cement neat paste.The prepared cement-based diaphragm can be applied to super
capacitor,
hybrid super
capacitor and battery.The
energy storage device includes tab, positive
electrode, negative
electrode and cement-based diaphragm after etching and impregnated with
electrolyte between two electrodes.The preparation process of the cement-based diaphragm is simple and reasonable, convenient to operate, can improve the
porosity of cement neat paste, provide more channels for the transmission of ions in its interior, thereby improve the
ion conductivity of cement neat paste, so that it can have better
energy storage performance when used as diaphragm.