The invention discloses a
microcrystalline glass substrate with metalized through holes and a preparation method of the
microcrystalline glass substrate, and belongs to the field of electronic device adapter plate manufacturing. The substrate comprises a microcrystal glass plate base material and a through hole vertically penetrating through the upper and lower planes of the microcrystal glass plate base material, and a metalized conductive structure is formed in the through hole. The preparation method comprises the following steps: performing
irradiation modification on a selected area of a
microcrystalline glass thin plate by adopting CO2 pulse
laser to convert microcrystals in the thin plate into an
amorphous phase, and then selectively and efficiently
etching a
laser modified columnar area in a corrosive liquid to form a through hole; the inner wall of the through hole is activated by SnCl2 in the later period, chemical
nickel plating is conducted, annealing is conducted to form a seed layer so that the through hole can be filled through electro-coppering, and finally chemical mechanical
polishing is used for removing
metal on the surface of the microcrystal thin plate to complete preparation. According to the invention, the problem of
processing the through hole of the microcrystalline glass is solved, and meanwhile, the
palladium-free activation process is adopted, so that the cost is remarkably reduced, and an ideal substrate solution is provided for
electronic packaging with high performance, high reliability and high
cost performance.