The invention provides a
luminescent material containing a cyclobutadiene structure, and a preparation method and application thereof, and relates to the technical field of organic electroluminescent materials. According to the cyclobutadiene-containing
luminescent material provided by the invention, the anti-aromatic cyclobutadiene is fused into a binary
nitrogen-containing fused heterocyclic skeleton, and excitation state vibration relaxation is inhibited by using the special
electronic structure and high ring tension of the anti-aromatic cyclobutadiene, so that narrow-band
luminescence is realized. By introducing the steric hindrance effect group, the aggregation
fluorescence quenching phenomenon between luminescent parent nuclei is weakened, and the
fluorescence quantum yield is improved. Different from a current mainstream multi-
resonance mechanism, the design of the narrow-
spectrum light-emitting molecule provided by the invention does not need to depend on the construction of a B / N-fused ring, and the molecular structure can be simplified to realize full-light-color ultra-narrow-band
light emission. When the organic light-emitting
diode is applied to an organic light-emitting device, an ultra-narrow full-width-at-half-peak electroluminescent spectrum and high device efficiency can be realized, and a better solution is provided for an ultra-high-definition organic light-emitting
diode display technology.