The application provides a
luminescent material containing a cyclobutadiene structure, a preparation method and application, and relates to the technical field of organic electroluminescent materials.The
luminescent material containing a cyclobutadiene provided by the application is fused to a binary
nitrogen-containing fused heterocyclic skeleton by using anti-aromatic cyclobutadiene, the anti-aromatic special
electronic structure and high ring tension of the anti-aromatic cyclobutadiene are utilized to inhibit
excited state vibration relaxation and realize narrow-band
luminescence.By introducing a steric hindrance effect group, the aggregation-induced
fluorescence quenching phenomenon between luminescent mother nuclei is weakened, and the
fluorescence quantum yield is improved.Different from the current mainstream
multiple resonance mechanism, the narrow-spectrum luminescent molecule design provided by the application does not need to depend on the construction of B / N-hetero-fused rings, and the molecular structure can be simplified to realize full-color super-narrow-band
luminescence.The application is applied to an organic electroluminescent device, and can realize an electroluminescent spectrum with a super-narrow
full width at half maximum and high device efficiency, and provides a better solution for super-high-definition organic light-emitting
diode display technology.