The invention provides a black ink for ink-jet printers, which comprises 10-30% of carbon black, 0.1-1.25% of amphiprotic polymerized substance, 0.1-1.5% of levelling agent, 10-30% of wetting agent, 0.05%-0.5% of defoaming agent and deionized water, 20-33% of carbon black dispersion liquid, 0.05-2% of surface active agent, 5-50% of humectant, 0.1-2% of pH regulator, 0.5-2% of drier, 0.1-0.5% of preservative agent, 0.1-0.5% of mold preventive, 0.01-0.5% of chelating agent, 0.1-2% of resin and deionized water.