The invention relates to a fluorine gas purifying filler and a preparation method and application thereof, the filler is a fluoride salt filler, and the fluoride salt is a mixture of one or more of sodium fluoride, potassium fluoride, calcium fluoride, magnesium fluoride, lithium fluoride. The filler is prepared from the fluoride salt and hydrofluoric acid with a concentration of no less than 5% by mixing, reaction, curing, molding, air-drying and roasting, the internal porosity of the filler is 40%-60%, has the characteristics of large porosity and strong skeleton, and has the characteristics of strong adsorption and good purification effect when used in fluorine gas purification, and the preparation method of the fluorine gas purifying filler is simple and easy to implement.