The invention provides an MOF-based nano positive
electrode material and application thereof in an aqueous
zinc ion battery, and relates to the field of
electrochemical energy storage devices, and the MOF-based nano positive
electrode material comprises a bimetallic MOF which is formed by bimetallic cluster nodes composed of
divalent manganese ions and trivalent
vanadium ions; the organic ligand is a polydentate
carboxylic acid ligand containing a rigid aromatic ring structure, the organic ligand and the bimetallic
cluster node are in coordination connection to form a three-dimensional frame structure, and the three-dimensional frame structure is provided with hierarchical pore channels. According to the MOF-based nano positive
electrode material, a three-dimensional continuous
conductive coating layer is constructed on the surface of a
bimetal MOF by adopting
nitrogen-
doped carbon nanofibers, Mn-N and V-N coordination bonds are formed at an interface, firm heterogeneous
interface bonding and an efficient
electron transport network are realized, the mechanical stress of electrode particles is effectively buffered in the circulation process, and the electrochemical performance of the electrode particles is improved. The conductive network is prevented from
cracking or falling off, and the overall conductive continuity of the electrode is ensured.