The invention provides a 5-substituted 2, 2-dimethyl-1, 3-indandione derivative and a 5, 6-substituted 2, 2-dimethyl-1, 3-indandione derivative; the structural formulas of the two derivatives are described in the description, wherein R, R1 and R2 respectively represent an
electron-rich
aromatic amine substituent group containing at least one
nitrogen, amino
nitrogen is connected with 2, 2-dimethyl-1, 3-indandione, or R2 represents a substituted aromatic hydrocarbyl; the invention also provides a preparation method of the 5-substituted 2, 2-dimethyl-1, 3-indandione derivative and a preparation method of the 5, 6-substituted 2, 2-dimethyl-1, 3-indandione derivative; an
organic electroluminescence device which takes an organic thin film layer formed by the 5-substituted 2, 2-dimethyl-1, 3-indandione derivative or the 5, 6-substituted 2, 2-dimethyl-1, 3-indandione derivative as a luminescent layer has the advantages of being driven by
low voltage, being high in efficiency, stable in
luminescence and long in service life, and the like.