The invention relates to an intelligent nano anti-pollution coating spraying system. A quantitative liquid spraying system of the intelligent nano anti-pollution coating spraying system is formed by sequentially connecting a liquid accumulating tank, a filter, a meter pump, a pressure meter, a back pressure valve, stop valves, a damper, an electromagnetic valve, a calibrating tube, an air compressor, a pressure regulating valve, a check valve, a gas spray nozzle, a pluggable movable joint, a tee and an elbow through stainless steel water tubes and plastic hoses; an intelligent motion control system comprises screw rods, screw rod nuts, sliding tracks, sliding blocks, connecting rods, a support, a bearing seat, a bearing, stepping motors, couplers and a rack which are arranged in the longitudinal direction and the horizontal direction; a longitudinal connecting rod is fixed on a longitudinal screw rod nut and a sliding block of a longitudinal sliding track simultaneously, and a horizontal connecting rod is fixed on a horizontal screw rod nut and a sliding block of a horizontal sliding track simultaneously; one end of each of a longitudinal screw rod and a horizontal screw rod is fixed on the rack through the bearing and the bearing seat, and the other ends of the longitudinal screw rod and the horizontal screw rod are connected with the stepping motors fixed on the rack through the couplers; and two ends of each of the sliding tracks are fixed on the rack through the support.