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77 results about "Electron paramagnetic resonance" patented technology

Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials with unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but it is electron spins that are excited instead of the spins of atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes or organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford.

System and method for electron spin resonance

A resonator system for electron spin resonance (ESR) is disclosed. The resonator system comprises: a generally planar resonator layer defining an open-loop gapped by a non-conductive gap in the layer, and a microwave feed, positioned configured for transmitting microwave to the resonator layer such as to concentrate, with a quality factor of at least 100, a magnetic field within an effective volume of less than 1 nL above the layer.
Owner:TECHNION RES & DEV FOUND LTD

Semiconductor device

Electric characteristics of a semiconductor device using an oxide semiconductor are improved. Further, a highly reliable semiconductor device in which a variation in electric characteristics with time or a variation in electric characteristics due to a gate BT stress test with light irradiation is small is manufactured. A transistor includes a gate electrode, an oxide semiconductor film overlapping with part of the gate electrode with a gate insulating film therebetween, and a pair of electrodes in contact with the oxide semiconductor film. The gate insulating film is an insulating film whose film density is higher than or equal to 2.26 g / cm3 and lower than or equal to 2.63 g / cm3 and whose spin density of a signal with a g value of 2.001 is 2×1015 spins / cm3 or less in electron spin resonance.
Owner:SEMICON ENERGY LAB CO LTD

Control and readout of electron or hole spin

This invention concerns an electronic device for the control and readout of the electron or hole spin of a single dopant in silicon. The device comprises a silicon substrate in which there are one or more ohmic contact regions. An insulating region on top of the substrate. First and second barrier gates spaced apart to isolate a small region of charges to form an island of a Single Electron Transistor (SET). A third gate over-lying both the first and second barrier gates, but insulated from them, the third gate being able to generate a gate-induced charge layer (GICL) in the ESR line substrate beneath it. A fourth gate in close proximity to a single dopant donor gate atom, the dopant atom being encapsulated in the substrate outside the region of the GICL but close enough to allow spin-dependent charge tunnelling between the dopant atom and the SET island under the control of gate potentials, mainly the fourth gate. In use either the third or fourth gate also serve as an Electron Spin Resonance (ESR) line to control the spin of the single electron or hole of the dopant atom. In a further aspect it concerns a method for using the device.
Owner:NEWSOUTH INNOVATIONS PTY LTD

Method of and apparatus for in-situ measurement of changes in fluid composition by electron spin resonance (ESR) spectrometry

A miniaturized instrument and method of using electron spin resonance spectrometry for measuring the degradation of lubricating fluids, and the like, that includes continuously passing a sample of such fluid through a resonating RF microwave cavity resonator during the application therethrough of a uniform slowly varying uniform magnetic field that is rapidly modulated and measuring the resulting phase modulation or amplitude modulation thereof to derive an electron spin resonance signal that directly senses the molecular changes in the fluid sample resulting from fluid degradation during operation of the vehicle, such as peroxy radicals in vehicle engine oil and the like.
Owner:ACTIVE SPECTRUM

Method of stabilizing fluorine-containing polymer

InactiveUS6451962B1Length can be shortenedShorten treatment timePolymer scienceShell molding
To provide the stabilization method, in which unstable groups of melt-processable fluorine-containing polymer having unstable groups can be stabilized rapidly and effectively, and even if the obtained stabilized polymer is melt-molded, an obtained molded article is free from bubbles and cavity and no coloration arises. The method of stabilizing a fluorine-containing polymer by melt-kneading a melt-processable fluorine-containing polymer having unstable groups in a kneader having a stabilization treatment zone which satisfies the following conditions:(1) an oxygen-containing gas is present in the stabilization treatment zone,(2) water is present in the stabilization treatment zone, and(3) an absolute pressure in the stabilization treatment zone is adjusted to a pressure of 0.2 MPa or more or (a) an oxygen-containing gas is present in the stabilization treatment zone in a sufficient amount that the fluorine-containing polymer after the stabilization treatment has the number of carbon radical spins measured by an electron spin resonance absorption analysis at a temperature of 77 K of not more than 5x1013 spin / g, and (b) water is present in the stabilization treatment zone.
Owner:DAIKIN IND LTD

Method of extracting and purifying melanin from almond peel

The invention discloses an extracting method and purifying method of melanin from almond peel, which comprises the following steps: adopting almond peel as raw material; extracting through alkaline solution; hydrolyzing impurity through acid; purifying through reciprocal organic solvent washing and alkaline dissolving to sediment; freezing; defreezing; washing through deionized water to remove Cl-; drying in the vacuum; obtaining the product.
Owner:NORTHWEST A & F UNIV

Downhole micro magnetic resonance analyzer

A downhole micro MR analyzer for use in a wellbore, having a micro sample tube, a micro RF coil in close proximity to the micro sample tube, and one or more magnets disposed about the micro sample tube is disclosed. The micro MR analyzer can be used for nuclear magnetic resonance or electron spin resonance experiments to ascertain formation properties and chemical compositions.
Owner:SCHLUMBERGER TECH CORP

Semiconductor device

A highly reliable semiconductor device the yield of which can be prevented from decreasing due to electrostatic discharge damage is provided. A semiconductor device is provided which includes a gate electrode layer, a first gate insulating layer over the gate electrode layer, a second gate insulating layer being over the first gate insulating layer and having a smaller thickness than the first gate insulating layer, an oxide semiconductor layer over the second gate insulating layer, and a source electrode layer and a drain electrode layer electrically connected to the oxide semiconductor layer. The first gate insulating layer contains nitrogen and has a spin density of 1×1017 spins / cm3 or less corresponding to a signal that appears at a g-factor of 2.003 in electron spin resonance spectroscopy. The second gate insulating layer contains nitrogen and has a lower hydrogen concentration than the first gate insulating layer.
Owner:SEMICON ENERGY LAB CO LTD

System and method for measuring resonant frequency of near-field microwave resonator

The invention relates to a system and method for measuring resonant frequency of near-field microwave resonator, which utilizes electron spin resonance and diamond nitrogen vacancy defect (NV color center) to pull the oscillation frequency and the intensity of the microwave to place the diamond in a static magnetic field. In the process, the microwave pulse frequency and the magnetic field intensity are changed to perform photodetection magnetic resonance and rabbi oscillation measurement, and a series of rabbi oscillation frequencies are obtained, from which the resonator resonance frequencyis extracted. The measuring system comprises an optical module, a microwave module, a magnetic field device, a diamond and a control device, wherein the diamond is embedded with a NV color core; theoptical module can generate and guide light to the diamond, and simultaneously detect the fluorescent signal emitted by the diamond. The microwave module can generate a microwave control field and load it onto the diamond. The magnetic field device can generate a static magnetic field. The invention can measure the resonant frequency and the effective magnetic field strength of the microwave resonator practically and accurately, has high precision, and can be used under near-field conditions.
Owner:BEIHANG UNIV

Exciton-plasmon coupling system, construction method thereof and method for enhancing photosensitizer singlet oxygen generation by coupling system

The invention relates to an exciton-plasmon coupling system, a construction method thereof and a method for enhancing photosensitizer singlet oxygen generation by the coupling system. The exciton-plasmon coupling system is of a core-shell structure formed by adsorbing photosensitizer exciton and plasmon nano-particles, and the LSPR (localized surface plasmon resonance) absorption peak of the plasmon nano-particles covers the exciton absorption peak of photosensitizer in a visible region. The method includes the step of selecting the peak position and the concentration of the plasmon nano-particles, the type and the concentration of electrified substances and the peak position and the concentration of the photosensitizer to form the stable coupling system. The singlet oxygen yield of products is measured by an electron spin resonance technique, the coupling effect as a main factor for enhancing photosensitizer singlet oxygen yield is determined by measuring Raman spectra, and results show that the exciton-plasmon coupling system has higher singlet oxygen yield as compared with an uncoupling system.
Owner:THE NAT CENT FOR NANOSCI & TECH NCNST OF CHINA

Probe and system for electron spin resonance imaging

ESR imaging probe, system, and method are described. The probe is an ex-situ probe, the system comprises the probe and configured for operating the probe, and the method comprises detecting ESR from outside a resonator of the probe. An exemplary embodiment of a probe according to the invention comprises a cooled dielectric resonator, and one sided gradient coils. An exemplary embodiment of the system comprises source current that is configured to supply to the gradient coils currents of up to 100 A in pulses shorter than 1 μsec.
Owner:TECHNION RES & DEV FOUND LTD

Semiconductor device and manufacturing method thereof

InactiveUS8927990B2Reduce hydrogen concentrationOxygen vacancies in the oxide semiconductor film are increasedTransistorSemiconductor/solid-state device manufacturingHydrogen concentrationOxygen vacancy
Hydrogen concentration and oxygen vacancies in an oxide semiconductor film are reduced. Reliability of a semiconductor device which includes a transistor using an oxide semiconductor film is improved. One embodiment of the present invention is a semiconductor device which includes a base insulating film; an oxide semiconductor film formed over the base insulating film; a gate insulating film formed over the oxide semiconductor film; and a gate electrode overlapping with the oxide semiconductor film with the gate insulating film provided therebetween. The base insulating film shows a signal at a g value of 2.01 by electron spin resonance. The oxide semiconductor film does not show a signal at a g value of 1.93 by electron spin resonance.
Owner:SEMICON ENERGY LAB CO LTD

Method and apparatus for in-situ measurement of soot by electron spin resonance (ESR) spectrometry

An instrument and method using electron spin resonance spectrometry for measuring the concentration of airborne soot particles, and the like, that includes continuously passing a sample of exhaust gas through a resonating RF microwave cavity resonator during the application therethrough of a uniform slowly varying uniform magnetic field that is rapidly modulated and measuring the resulting phase modulation or amplitude modulation thereof to derive an electron spin resonance signal that directly senses the concentration of carbon free radicals produced as a result of inefficient combustion of hydrocarbons during operation of the vehicle or boiler. A further invention is the use of this signal for feedback control of the engine or boiler operating parameters to minimize or substantially eliminate particulate matter emissions.
Owner:ACTIVE SPECTRUM

Graphite material for a lithium ion secondary cell negative electrode, method of manufacturing same, and lithium ion secondary cell

A graphite material for a negative electrode of a lithium ion secondary cell is capable of suppressing capacity degradation caused by the repetition of charging and discharging cycles, storage in a charged state, floating charging and the like. A graphite material for a negative electrode of a lithium ion secondary cell, in which Lc (112), which is a crystallite size in a c-axis direction calculated from a (112) diffraction line measured using powder X-ray diffraction method, is within 4.0 nm to 30 nm, a carbon-derived spectrum appearing in electron spin resonance spectroscopy, which is measured using an X band, is in a range of 3200 gauss (G) to 3400 gauss (G), a relative signal intensity ratio (I4.8K / I40K) of the signal intensity (I4.8K) of the spectrum measured at a temperature of 4.8 K to the signal intensity (I40K) of the spectrum measured at a temperature of 40 K is within 1.5 to 3.0, and ΔHpp, which is a line width of the spectrum calculated from a primary derivative spectrum of the temperature of 4.8 K, is within 20 gauss (G) to 40 gauss (G).
Owner:JX NIPPON OIL & ENERGY CORP

Gas Barrier Film and Gas Barrier Laminate

The gas barrier film of the present invention is a gas barrier film comprising a base material, and an inorganic thin film composed of a silicon oxide film formed on one or both surfaces of the base material, wherein radical density of the Pb center of the silicon oxide film observed by an electron spin resonance method (ESR method) is from 1×1016 to 1×1019 spins / cm3, or a gas barrier film comprising a base material, an inorganic thin film containing silicon oxide and the other metal component formed on one or both surfaces of the base material, wherein radical density of the Pb center of the silicon oxide in the inorganic thin film observed by an ESR method is from 13×1014 to 3×1017 spins / mol, and a laminate wherein at least one paper and / or plastic film is laminated on the gas barrier film.
Owner:NAT INST OF ADVANCED IND SCI & TECH +1

Light-Emitting Element and Light-Emitting Device

Provided are a light-emitting element capable of reducing power consumption by increasing its light extraction efficiency and a light-emitting device using the light-emitting element. A light-emitting element includes a composite material, which contains an organic compound having a high hole-transport property and an electron acceptor and in which the spin density measured by an electron spin resonance (ESR) method is less than or equal to 1×1019 spins / cm3, the spin density is less than or equal to 3×1019 spins / cm3 when the molar ratio of the electron acceptor to the organic compound is greater than or equal to 1, or the spin density is less than or equal to 5×1019 spins / cm3 when the molar ratio is greater than or equal to 2.
Owner:SEMICON ENERGY LAB CO LTD

Semiconductor ceramic and method for manufacturing the same, and laminated semiconductor ceramic capacitor with varistor function and method for manufacturing the same

A semiconductor ceramic contains a donor element solid-solved in crystal grains of a SrTiO3-based compound, and an acceptor element in a grain boundary layer. The number of tetravalent acceptor elements is 1×1017 / g or more, as determined from an electron spin resonance absorption spectrum. A mixture of a calcined powder and an acceptor compound is pulverized to a specific surface area of 5.0 to 7.5 m2 / g before mixing with a binder. Semiconductor ceramic layers having a varistor function are formed by using the semiconductor ceramic forming a highly reliable capacitor which can suppress characteristics variations to stably obtain good electrical characteristics.
Owner:MURATA MFG CO LTD

Definition method for forming time of ductile shear zone

The invention relates to a definition method for the forming time of a ductile shear zone and in particular relates to a definition method for measuring the age of new alpha quartz in a mylonite substrate by an electron spin resonance method to define the forming time of the ductile shear zone. The method comprises the steps of (1) sample collection; (2) sample preparation; (3) sample measurement: measuring a balance uranium mole value and thermal activation ESR (electron spin resonance) spectrum amplitude; (4) calculating the forming time of the ductile shear zone. The method disclosed by the invention is simple and effective and has the advantages that test samples are readily available, the test cost is low and the like; the problems of long test period, high test cost and the like of the conventional definition method can be solved.
Owner:HEFEI UNIV OF TECH

Semiconductor device and manufacturing method thereof

Hydrogen concentration and oxygen vacancies in an oxide semiconductor film are reduced. Reliability of a semiconductor device which includes a transistor using an oxide semiconductor film is improved. One embodiment of the present invention is a semiconductor device which includes a base insulating film; an oxide semiconductor film formed over the base insulating film; a gate insulating film formed over the oxide semiconductor film; and a gate electrode overlapping with the oxide semiconductor film with the gate insulating film provided therebetween. The base insulating film shows a signal at a g value of 2.01 by electron spin resonance. The oxide semiconductor film does not show a signal at a g value of 1.93 by electron spin resonance.
Owner:SEMICON ENERGY LAB CO LTD

Method and device for capturing free radicals in transient state generated by discharge of plasma in low temperature

A method for gathering transient free radical generated by low temperature plasma discharge includes reacting transient gas phase free radial generated by low temperature plasma coronal discharge with spin gathering agent in solution to form spin additive matters under average electric field intensity of 4-10kv / cm, taking 0.1-0.2mL gathering solution after reaction and filling said solution in quarts sample bottle for carrying out detection by spin resonator, using ESR spectral line form of spin additive matters to confirm type of free radical and using spectral line signal intensity to confirm content of free radical.
Owner:ZHEJIANG UNIV

Carbon fiber, process for production of polyacrylonitrile-base precursor fiber for carbon fiber production, and process for production of carbon fiber

A process for the production of polyacrylonitrile-base precursor fiber for carbon fiber production which comprises spinning a spinning dope containing a polyacrylonitrile-base polymer having a limiting viscosity of 2.0 to 10.0 in a concentration of 10 to 25% by weight by a wet spinning method or a dry-wet spinning method, subjecting the obtained fiber to drying and heat treatment, and then steam-stretching the resulting fiber, wherein the extrusion linear speed of the polyacrylonitrile-base polymer from spinnerets is 2 to 15m / min; and a carbon fiber which is produced by firing the polyacrylonitrile-base precursor fiber obtained by the process and which has a strand tensile modulus of 320 to 380GPa and a conduction electron density of 3.0*10<19> to 7.0*10<19>spins / g as determined by electron spin resonance.
Owner:TORAY IND INC
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