The invention provides a preparation method of ultralow-
nitrogen-content high-
vanadium iron. The preparation method comprises the following steps that S1,
silicon iron powder is laid at the bottom of high-
vanadium iron preparation equipment; s2, burdening according to the composition proportion of the high-
vanadium iron, and electrifying the burdened raw materials for arcing and
smelting; and S3, after
smelting is finished, electrifying is stopped, then a refining agent is blown to the
slag layer, submerged arc electrifying heating continues after blowing is finished, then
nitrogen is removed from the
slag surface, and finally obtained high-vanadium iron is quenched. In the preparation method of the ultralow-
nitrogen-content high-ferrovanadium, the
sulfur load and the carbon load in a ferrovanadium
system are reduced by adopting a high-proportion low-
sulfur flake vanadium furnace burden and further combining the means of strengthening
slag refining, shortening the electrifying
smelting time and the like, and meanwhile, submerged arc electrifying heating is performed in a slag layer so as to reduce the
ionization effect of a
graphite electrode arc on nitrogen in air; therefore, the nitrogen content in the
ferrovanadium alloy is reduced, and finally the N content in the ferrovanadium is smaller than or equal to 0.04%.