The invention discloses a 
polypyrrole microelectrode with three-dimensional structure which belongs to the technical field of the micro-electro-mechanical preparation and is used in the miniature 
supercapacitor, and a preparation method thereof. The preparation method of the 
microelectrode comprises the following steps: adopting the MEMS technology to coat a SU-8 
epoxy group negative chemically amplified 
resist on the surface of a 
copper substrate, performing spin-
coating, pre-baking, lithographic process treatment, 
exposure, post-baking, development, rinsing and 
heat setting to form a columnar structure which is prepared from SU-8 
photoresist and is in an array arrangement, on the surface of the 
copper substrate, and covering a functional film composed of 
polypyrrole and conductive material on the surfaces of the 
copper substrate and the microcolumn array 
microelectrode. The invention solves the problems that the common 
polypyrrole electrode with a two-dimensional structure can not store a large quantity of charges, have high 
internal resistance and the like, thus improving the 
energy storage characteristic and large current 
discharge performance of the miniature 
supercapacitor. The miniature 
supercapacitor of the invention has wide application prospect in the fields of sensor network node power supply, micro-
robot driving power and 
fuze power.