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40 results about "Thiirane" patented technology

Thiirane, more commonly known as ethylene sulfide, is the cyclic chemical compound with the formula C₂H₄S. It is the smallest sulfur-containing heterocycle and the simplest episulfide. Like many organosulfur compounds, this species has a stench. Thiirane is also used to describe any derivative of the parent ethylene sulfide.

High sulfur content copolymers and composite materials and electrochemical cells and optical elements using them

The present invention relates generally to high sulfur content polymeric materials and composites, methods for making them, and devices using them such as electrochemical cells and optical elements. In one aspect, a polymeric composition comprising a copolymer of sulfur, at a level in the range of at least about 50 wt % of the copolymer, and one or more monomers each selected from the group consisting of ethylenically unsaturated monomers, epoxide monomers, and thiirane monomers, at a level in the range of about 0.1 wt % to about 50 wt % of the copolymer.
Owner:THE ARIZONA BOARD OF REGENTS ON BEHALF OF THE UNIV OF ARIZONA

Watersoluble polyurethane adsorption agent containing sulfhydryl group for removing hydrargyrum and preparation method thereof

The present invention pertains to the technical field of wastewater treatment, in particular to hydrophilic polyurethane absorbent containing sulfhydryl for removing Hg and a preparation method thereof. The present invention takes water and volatile non-water solvent as the mixed solvent, introduces chloromethyl thiirane monomer as the cross linking agent into hydrophilic polyurethane dispersion dope and finally carries out coating and solidification, thus obtaining the hydrophilic polyurethane absorbent containing sulfhydryl. The present invention has the advantages of simple and convenient technique, high production efficiency, high product quality and low cost. The composition of the prepared absorbent is controllable with the size of 50 to 250mm, the prepared absorbent has the advantages of large specific surface area, strong Hg-ion absorption capacity and rapid absorption rate. In addition, the present invention with excellent high-concentration Hg-ion absorption capacity and trace Hg-ion absorption capacity, good mechanical property and damage ratio lower than 0.5 percent after being used for a plurality of times can be applied to Hg, lead, cadmium and other heavy metal industrial wastewater treatment within a more extensive concentration range.
Owner:TONGJI UNIV

Sulfur composites and polymeric materials from elemental sulfur

Sulfur composites and polymeric materials having a high sulfur content and prepared from elemental sulfur as the primary chemical feedstock. The sulfur copolymers are prepared by the polymerization of elemental sulfur with one or more monomers of amines, thiols, sulfides, alkynylly unsaturated monomers, nitrones, aldehydes, ketones, thiiranes, ethylenically unsaturated monomers, or epoxides. The sulfur copolymers may be further dispersed with metal or ceramic composites or copolymerized with elemental carbon, photoactive organic chromophores, or reactive and solubilizing / biocompatible moieties. The sulfur composites and polymeric materials feature the ability self-healing through thermal reformation. Applications utilizing the sulfur composites and polymeric materials may include electrochemical cells, optics, H2S donors and antimicrobial materials.
Owner:THE ARIZONA BOARD OF REGENTS ON BEHALF OF THE UNIV OF ARIZONA

Aromachemicals

Improved aromachemical derivatives, and fragrances and flavorings including the derivatives, that have a longer useful shelf life than the aromachemicals from which they can be derived, are disclosed. In particular, the derivatives maintain the fragrance characteristics of the aromachemicals, while lowering the allergic properties, increasing the stability, and / or increasing the odor intensity. Also disclosed are methods of making the derivatives, and articles of manufacture including the derivatives. In one embodiment, the derivatives are prepared by replacing one or more double bonds in citral with a thioether, cyclopropyl, oxirane, or thiirane group. The cyclopropane ring can be unsubstituted, or substituted with one or two lower alkyl, preferably methyl groups. The alkyl groups can optionally be substituted, for example, with electron donating groups, electron with drawing groups, groups which increase the hydrophilicity or hydrophobocity, and the like. In another embodiment, the derivatives are prepared by replacing the aldehyde group in the essential oil with a nitrile, methyl ether or acetal group. The acetal groups can provide the compounds with a long lasting flavor or fragrance, where the acetals slowly hydrolyze to provide the aldehyde group in the parent essential oil. In some embodiments, both the aldehyde and at least one of the double bond functional groups are both derivatized as described herein. Examples of suitable articles of manufacture include candles, air fresheners, perfumes, disinfectant compositions, hypochlorite (bleach) compositions, beverages such as beer and soda, denture cleanser tablets and flavored orally-delivered products such as lozenges, candies, and the like.
Owner:FLEXITRAL INC

Method for preparing N, N-diethylamino ethanethiol

The present invention relates to a method for preparing N, N-diethylamino ethanethiol, belonging to a chemical technical field. The method includes steps of a. heating rhodanides and ethylene carbonate to react under ordinary pressure, distilling to obtain Thiirane after the reaction, the general formula of the rhodanides is M-SCN, wherein M is alkali metal of Na or K; b. mixing and stirring the Thiirane and diethylamine in a toluene dissolvant, heating under an ordinary pressure to implement a backflow reaction and distilling to obtain the N, N-diethylamino ethanethiol after the backflow reaction. The method has a short synthesis technical process, the kind of the raw materials is few and source is wide, the used toluene dissolvant may be recovered, and there will generate little waste water, waste gas and waste which may reduce environmental pollution.
Owner:赵云现

Synthesis technology for N,N-diethylamino group ethanethiol

ActiveCN102153494ANothing producedFeeding molar ratio is too smallThiol preparationMaterial typeNitrogen
The invention discloses a synthesis technology for N,N-diethylamino group ethanethiol. The synthesis technology includes the steps of pressing ethane episulfide and diethylamine into a pressure reaction kettle by nitrogen, heating to the temperature of 80-100 DEG C in a closed state under the condition of stirring, and reacting for 3-5 hours to obtain the N,N-diethylamino group ethanethiol. The synthesis technology is finished in the closed reaction kettle by adopting the technical conditions as above, does not use any dissolvent or catalyst, does not generate by-product, and has the advantages of short technology flow, few material types, short reaction time and small excess of feed mole ratio of diethylamine to ethane episulfide; the mass percent of the prepared product can achieve 99%; and the whole production technology has the characteristics of low production cost, high yield, no exhaust of three wastes (waste gas, waste water, industrial residual), and the synthesis technology belongs to an environment-friendly chemical-industrial synthesis technology.
Owner:保定加合精细化工有限公司

Method for synthesizing N,N-diethylamino ethanethiol

The invention relates to a synthetic method for N, N-diethylaminoethanethiol, comprising the following step: the N, N-diethylaminoethanethiol is prepared after mixing ethylene sulfide and diethylamine under the condition of adding catalyst and heating the mixture to 50-80 DEG C for reaction. In the method, under the condition of presence of the catalyst, the raw materials can fully react without using any solvent and the ethylene sulfide can be effectively prevented from self polymerization, thus obtaining the products with high yield and quality. Meanwhile, without producing the three wastes, the method effectively protects the environment.
Owner:河北远大九孚生物科技有限公司

Coating composition, coating film made of same, and optical article

There is provided a coating composition having a good wetting property which is capable of forming a coating film exhibiting a high refractive index, a less discoloration, and excellent transparency and uniformity when polymerized and cured. The present invention relates to a coating composition comprising (A) 100 parts by weight of a thiirane ring-containing compound, (B) 0.0001 to 10 parts by weight of a catalyst for accelerating polymerization of the thiirane ring-containing compound, and (C) 0.005 to 4 parts by weight of a modified silicone oil; a coating film produced from the composition; and an optical product provided with the coating film.
Owner:MITSUBISHI GAS CHEM CO INC

Process for synthesizing diethylaminoethyl mercaptide

The invention discloses a process for synthesizing diethylaminoethyl mercaptide. The process comprises the following steps: pretreating raw materials, preparing thiirane through the reaction of potassium sulfocyanide and ethylene carbonate, and finally synthesizing the thiirane and diethylamine into the product of diethylaminoethyl mercaptide. In the synthesis process, pretreatment is firstly carried out on the raw materials, a sectional heating mode is adopted during synthesis reaction so as to enable the reactants to be reacted completely, no solvents or catalysts are added in the whole process, pressurizing is not required, the yield and purity of the product are high, three wastes are not generated, and the process is environment-friendly.
Owner:张丽学

Preparation method and application of modified superparamagnetic Fe3O4 nanoparticle

The invention discloses a preparation method and application of a modified superparamagnetic Fe3O4 nanoparticle, belonging to the field of treatment of industrial wastewater. The method comprises the following steps of preparing the superparamagnetic Fe3O4 nanoparticle by adopting a coprecipitation method; by taking superparamagnetic Fe3O4 as a core, coating the surface of Fe3O4 with one or more layers of silica shells by adopting hydrolysis; modifying coated silica by applying a coupled reaction principle; by taking 3-aminopropyl trimethoxysilane as a modification reagent, modifying on a core-shell structure and connecting to an amino group; finally, using chloromethyl thiirane to synthesize a chelate which simultaneously contains nitrogen and sulfur by a nucleophilic substitution reaction; then using the chelate to adsorb heavy metal mercury, and in particular to selectively adsorb Hg<2+> at normal temperature, wherein the adsorption efficiency of the chelate is significantly higher than that of a chelate which is previously synthesized and only contains a sulfur ligating atom. The modified superparamagnetic Fe3O4 nanoparticle has the advantage of easiness in recovery and regeneration.
Owner:KUNMING UNIV OF SCI & TECH

Mycobacterium applied for fuel oil thiirane desulfuration and uses thereof

The present invention discloses one kind of bacterial strain for desulfurizing sulfur-containing heterocyclic ring compound in fuel oil. The bacterial strain is named as Mycobacterium ZD-19, and has the preservation number of CGMCC No. 1817. The present invention also discloses the specific desulfurizing use of eliminating sulfur-containing heterocyclic ring compound in fuel oil. By means of biological desulfurizing technology with the strain as the catalyst, sulfur-containing heterocyclic ring compound in fuel oil is degraded. The process of degrading dibenzothiophene and its derivative 4, 6-dimethyl dibenzothiophene follows one unique 'expanded 4S path', and the traditional 'expanded 4S path' products 2-hydroxy biphenyl and 3, 3'-dimethyl-2-hydroxy biphenyl are further methylated to produce final products 2-methoxyl biphenyl and 3, 3'-dimethyl-2- methoxyl biphenyl in effectively reduced product inhibition.
Owner:ZHEJIANG UNIV

Bacillus subtilis and application thereof

The invention provides a strain of bacillus subtilis SWS3, which is preserved in China Center for Type Culture Collection on November 1, 2021, the preservation address is Wuhan University, and the preservation number is CCTCC M 20211349; the strain can be used for effectively degrading methyl mercaptan, 2-methyl episulfide ethane, butyric acid, valeric acid and eudesmol; the strain can degrade volatile substances in the kitchen waste low-temperature vacuum drying condensate within 48 hours, and the COD (Chemical Oxygen Demand) of the condensate is reduced from 2283 mg.L <-1 > to 134 mg.L <-1 >, so that the condensate directly meets the wastewater discharge standard.
Owner:BIOLOGY INST OF SHANDONG ACAD OF SCI +1

Negative photoresist

The invention discloses a negative photoresist which comprises the following components in parts by mass: 100 parts of transparent high-refractive index photosensitive alkali-soluble resin A, 0.005-20 parts of photoinitiator B, 10-80 parts of reactive diluent C, and 20-60 parts of solvent D; the transparent high-refractive index photosensitive alkali-soluble resin A is obtained by modifying cycloaliphatic thiirane diacrylates resin a1 through an anhydride curing agent a2; the cycloaliphatic thiirane diacrylates resin a1 is formed by copolymerizing cycloaliphatic episulfide monomer a11 and allyl acrylic acid compound a12; the cycloaliphatic episulfide monomer a11 is obtained by displacing cycloaliphatic epoxy monomer a111. According to the negative photoresist, the resin is guaranteed to have photosensitivity, alkali solubility characteristics and the like, the system is transparent, the refractive index of the resin can be improved, the resin can be effectively applied into the negative photoresist, and the vanishing characteristic of the photoresist can be increased.
Owner:SHENZHEN DALTON ELECTRONICS MATERIAL CO LTD

Synthesis of 1,3-terahydro thiazolone compound

The present invention relates to the synthesis of 1,3-tetrahydro thiazolone-2 compounds as important intermediate for farm pesticide and some medicines. Compound 1,3-tetrahydro thiazothione-2 and epoxy ethane as materials are reacted. The solvent used in the reaction is at least one of water, C1-C4 fatty alcohol, C1-C4 fatty ketone, C1-C4 fatty ester, benzene, toluene, tetrahydrofuran, acetonitrile, dimethylformamide and dimethyl sulfoxide. The present invention has simple reaction condition, high product purity and high industrial application value. Through selecting and regulating solvent, epithioethane or polyglycol sulfide product may be obtained at the same time.
Owner:CHENGDU KAOENSI SCI & TECH

Method for continuously producing ethylene sulfide

The invention provides a method for continuously producing ethylene sulfide. The method comprises the following steps of: forming a substrate; continuously adding ethylene carbonate and thiocyanate into a continuous reactor of which the temperature is controlled to be 90-140 DEG C; carrying out a reaction to generate ethylene sulfide and cyanate under the stirring action, continuously dischargingthe generated ethylene sulfide from a gas outlet of the reactor, and carrying out condensation and separation to obtain liquid ethylene sulfide, and continuously discharging the generated cyanate fromthe bottom of the reactor. Through continuous reaction, an intermittent kettle type reaction in the prior art is improved into a continuous reactor, raw materials instantaneously react at the reaction temperature, generated epithioethane is rapidly separated from other substances, and generated cyanate powder is discharged from the bottom of the reactor under the action of gravity and screw propulsion of a stirrer by a wall scraping screw. The method is clean, pollution-free, stable in production index, low in labor consumption and beneficial to industrial scale-up production.
Owner:保定加合精细化工有限公司

A preparation method and application of modified superparamagnetic iron tetraoxide nanoparticles

The invention discloses a preparation method and application of a modified superparamagnetic Fe3O4 nanoparticle, belonging to the field of treatment of industrial wastewater. The method comprises the following steps of preparing the superparamagnetic Fe3O4 nanoparticle by adopting a coprecipitation method; by taking superparamagnetic Fe3O4 as a core, coating the surface of Fe3O4 with one or more layers of silica shells by adopting hydrolysis; modifying coated silica by applying a coupled reaction principle; by taking 3-aminopropyl trimethoxysilane as a modification reagent, modifying on a core-shell structure and connecting to an amino group; finally, using chloromethyl thiirane to synthesize a chelate which simultaneously contains nitrogen and sulfur by a nucleophilic substitution reaction; then using the chelate to adsorb heavy metal mercury, and in particular to selectively adsorb Hg<2+> at normal temperature, wherein the adsorption efficiency of the chelate is significantly higher than that of a chelate which is previously synthesized and only contains a sulfur ligating atom. The modified superparamagnetic Fe3O4 nanoparticle has the advantage of easiness in recovery and regeneration.
Owner:KUNMING UNIV OF SCI & TECH

Selective extracting method of rare earth cerium in bastnaesite

The invention discloses a selective extracting method of rare earth cerium in bastnaesite. According to the method, a coprecipitation method is adopted to prepare superparamagnetic ferroferric oxide nanoparticles, superparamagnetic ferroferric oxide serves as the core, hydrolysis is adopted to enable the surface of ferroferric oxide to be coated with a layer of or multiple layers of silicon dioxide shells, on the basis of the coupled reaction principle, the core coated with the coupled reaction is modified, 3-amidogen propyl trimethoxy silane serves as a modification reagent, the core shell structure is modified, and is connected with amidogen, finally, chloromethyl thiirane is used for synthesis through the nucleophilic substitution to form chelate containing nitrogen and sulfur at the same time, then, selective extraction of rare earth cerium in bastnaesite is carried out, at the normal temperature, Ce2+ is absorbed selectively, through the method, the defect that during previous solvent extraction, a solvent in solvent extraction is commonly an organic solvent, most of organic solvents are poisonous, and secondary pollution is easily caused is overcome, and the beneficial effects of being easy to recycle and free of pollution are achieved.
Owner:KUNMING UNIV OF SCI & TECH

Microspheric precious metal adsorbent and preparation method thereof

The invention discloses a microspheric precious metal adsorbent and a preparation method thereof, belonging to the technical field of adsorption. The microspheric precious metal adsorbent has uniform particles and a regular shape, contains sulfydryl and an amino group, has a space network structure, and is prepared by undergoing ring opening and condensation polymerization reactions on chloromethyl thiirane and para-phenylene diamine, suspending and polymerizing. The adsorbent is microspheric, can be filled into a columnar adsorbing device, has relatively high adsorption capacities on Au (III) and Ag (I), has high adsorbing performance on Hg (II) and Cu (II), and has relatively high practical utilization value.
Owner:JIANGNAN UNIV

Aromachemicals

Improved aromachemical derivatives, and fragrances and flavorings including the derivatives, that have a longer useful shelf life than the aromachemicals from which they can be derived, are disclosed. In particular, the derivatives maintain the fragrance characteristics of the aromachemicals, while lowering the allergic properties, increasing the stability, and / or increasing the odor intensity. Also disclosed are methods of making the derivatives, and articles of manufacture including the derivatives. In one embodiment, the derivatives are prepared by replacing one or more double bonds in citral with a thioether, cyclopropyl, oxirane, or thiirane group. The cyclopropane ring can be unsubstituted, or substituted with one or two lower alkyl, preferably methyl groups. The alkyl groups can optionally be substituted, for example, with electron donating groups, electron with drawing groups, groups which increase the hydrophilicity or hydrophobocity, and the like. In another embodiment, the derivatives are prepared by replacing the aldehyde group in the essential oil with a nitrile, methyl ether or acetal group. The acetal groups can provide the compounds with a long lasting flavor or fragrance, where the acetals slowly hydrolyze to provide the aldehyde group in the parent essential oil. In some embodiments, both the aldehyde and at least one of the double bond functional groups are both derivatized as described herein. Examples of suitable articles of manufacture include candles, air fresheners, perfumes, disinfectant compositions, hypochlorite (bleach) compositions, beverages such as beer and soda, denture cleanser tablets and flavored orally-delivered products such as lozenges, candies, and the like.
Owner:FLEXITRAL INC

Complete method for preparing diethylaminoethanethiol

A complete method for preparing diethylaminoethanethiol comprises the following steps: heating and drying thiocyanate by using a double-cone vacuum dryer, and cooling for later use after drying; carrying out cyclization reaction on ethylene carbonate and dried and heat-insulated sodium thiocyanate in a cyclization kettle to generate ethylene sulfide; and carrying out an addition reaction on the generated ethylene sulfide and excessive diethylamine in the addition kettle, putting the obtained reaction product into a distillation kettle, carrying out atmospheric distillation to collect unreacted diethylamine for direct recycling, carrying out reduced pressure distillation on the reaction product, and removing impurities to obtain the diethylaminoethanethiol. The preparation method of diethylaminoethanethiol is reasonable in process, green and environment-friendly, and high in product purity.
Owner:新疆上昵生物科技有限公司

Coating composition, coating film made of same, and optical article

There is provided a coating composition having a good wetting property which is capable of forming a coating film exhibiting a high refractive index, a less discoloration, and excellent transparency and uniformity when polymerized and cured. The present invention relates to a coating composition comprising (A) 100 parts by weight of a thiirane ring-containing compound, (B) 0.0001 to 10 parts by weight of a catalyst for accelerating polymerization of the thiirane ring-containing compound, and (C) 0.005 to 4 parts by weight of a modified silicone oil; a coating film produced from the composition; and an optical product provided with the coating film.
Owner:MITSUBISHI GAS CHEM CO INC

Aromachemicals

Improved aromachemical derivatives, and fragrances and flavorings including the derivatives, that have a longer useful shelf life than the aromachemicals from which they can be derived, are disclosed. In particular, the derivatives maintain the fragrance characteristics of the aromachemicals, while lowering the allergic properties, increasing the stability, and / or increasing the odor intensity. Also disclosed are methods of making the derivatives, and articles of manufacture including the derivatives. In one embodiment, the derivatives are prepared by replacing one or more double bonds in citral with a thioether, cyclopropyl, oxirane, or thiirane group. The cyclopropane ring can be unsubstituted, or substituted with one or two lower alkyl, preferably methyl groups. The alkyl groups can optionally be substituted, for example, with electron donating groups, electron with drawing groups, groups which increase the hydrophilicity or hydrophobocity, and the like. In another embodiment, the derivatives are prepared by replacing the aldehyde group in the essential oil with a nitrile, methyl ether or acetal group. The acetal groups can provide the compounds with a long lasting flavor or fragrance, where the acetals slowly hydrolyze to provide the aldehyde group in the parent essential oil. In some embodiments, both the aldehyde and at least one of the double bond functional groups are both derivatized as described herein. Examples of suitable articles of manufacture include candles, air fresheners, perfumes, disinfectant compositions, hypochlorite (bleach) compositions, beverages such as beer and soda, denture cleanser tablets and flavored orally-delivered products such as lozenges, candies, and the like.
Owner:FLEXITRAL INC

A kind of synthetic method of aminoethanethiol

The invention provides a method for synthesizing aminoethanethiol, a taurine intermediate. In the method, an addition reaction of ethylene sulfide and an ammonia compound is carried out under the catalysis of a modified supported metal catalyst to obtain aminoethanethiol. The method solves the problem of easy self-polymerization of ethylene sulfide after ring-opening, improves the yield and reduces the production cost.
Owner:WANHUA CHEM GRP CO LTD

Sulfur composites and polymeric materials from elemental sulfur

Sulfur composites and polymeric materials having a high sulfur content and prepared from elemental sulfur as the primary chemical feedstock. The sulfur copolymers are prepared by the polymerization of elemental sulfur with one or more monomers of amines, thiols, sulfides, alkynylly unsaturated monomers, nitrones, aldehydes, ketones, thiiranes, ethylenically unsaturated monomers, or epoxides. The sulfur copolymers may be further dispersed with metal or ceramic composites or copolymerized with elemental carbon, photoactive organic chromophores, or reactive and solubilising / biocompatible moieties. The sulfur composites and polymeric materials feature the ability self-healing through thermal reformation. Applications utilizing the sulfur composites and polymeric materials may include electrochemical cells, optics, H2S donors and antimicrobial materials.
Owner:THE ARIZONA BOARD OF REGENTS ON BEHALF OF THE UNIV OF ARIZONA

Synthesis method of aminoethanethiol

The invention provides a synthesis method of a taurine intermediate aminoethanethiol. According to the method, epithioethane and an ammonia compound are subjected to an addition reaction under the catalysis of a modified supported metal catalyst to obtain aminoethanethiol. According to the method, the problem that the epithioethane is easy to self-polymerize after ring opening is solved, the yield is improved, and the production cost is reduced.
Owner:WANHUA CHEM GRP CO LTD

Method for producing tiamulin by using diethylaminoethanethiol synthesis liquid

The invention relates to a chemical synthesis method of a raw material medicine for veterinary use, in particular to a method for producing tiamulin by using low-concentration diethylaminoethanethiol. The method comprises the following steps: reacting ethane episulfide with diethylamine to prepare a diethylaminoethanethiol synthetic solution, then directly reacting the diethylaminoethanethiol synthetic solution with p-toluene sulfonic acid pleuromutilin ester, and sequentially carrying out reductant reduction, alkaline washing, neutral washing, phase conversion and other extraction steps to prepare the high-purity tiamulin. According to the method, the diethylaminoethanethiol with the concentration of 25%-65% can directly react with the pleuromutilin p-toluenesulfonate to generate tiamulin so that the quality requirement on the diethylaminoethanethiol is greatly reduced, the safety of the production process is also greatly improved, the process is simple, the raw materials are easy to obtain, the cost is low, and thus the method is very suitable for industrial large-scale production.
Owner:新疆上昵生物科技有限公司

Mycobacterium applied for fuel oil thiirane desulfuration and uses thereof

The present invention discloses one kind of bacterial strain for desulfurizing sulfur-containing heterocyclic ring compound in fuel oil. The bacterial strain is named as Mycobacterium ZD-19, and has the preservation number of CGMCC No. 1817. The present invention also discloses the specific desulfurizing use of eliminating sulfur-containing heterocyclic ring compound in fuel oil. By means of biological desulfurizing technology with the strain as the catalyst, sulfur-containing heterocyclic ring compound in fuel oil is degraded. The process of degrading dibenzothiophene and its derivative 4, 6-dimethyl dibenzothiophene follows one unique 'expanded 4S path', and the traditional 'expanded 4S path' products 2-hydroxy biphenyl and 3, 3'-dimethyl-2-hydroxy biphenyl are further methylated to produce final products 2-methoxyl biphenyl and 3, 3'-dimethyl-2- methoxyl biphenyl in effectively reduced product inhibition.
Owner:ZHEJIANG UNIV
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