The embodiment of the invention provides a preparation method of a high-load
electrode with a vertical pore channel structure and a battery, which comprises the following steps:
grinding and premixing carbon
fluoride and a conductive carbon material in proportion, adding a binder, carrying out high-speed ball milling to obtain fiberized
powder, and rolling to prepare an
electrode material, thereby obtaining the high-load
electrode with the vertical pore channel structure. Compounding the carbon
fluoride with a
current collector through hot rolling to obtain a positive
pole piece; and finally, carrying out
laser pore-forming treatment on the positive
pole piece to obtain the high-load carbon
fluoride electrode with a vertical pore channel structure. The
pore diameter of the pore channel structure is 10-100 [mu] m, the pore
pitch is 1-10 times of the thickness of the
electrode material, the pore depth is 50-100% of the thickness of the
electrode material, the
ion tortuosity of the electrode is effectively reduced and the
ion transmission efficiency is improved by constructing a vertical pore channel, meanwhile, high-energy
laser induces an in-situ defluorination reaction on the pore wall to generate a high-
conductivity sp2 carbon phase, and the
conductivity of the electrode is improved. And the limitation of sacrifice
conductivity of a mechanical pore-forming technology is broken through.