The invention discloses a lithium-ion battery fire extinguishing agent and a preparation method thereof, and belongs to the technical field of fire extinguishing agents. The lithium-ion battery fire extinguishing agent is prepared from the following components in percentage by weight: 10-20% of dodecyl fluoride-2-methyl-3-pentanone, 15-35% of fluorocarbon surfactants, 10-15% of glycol, 1-3% of ethanol, 0.5-3% of polypropylene acid, and the balance of water. The preparation method of the lithium-ion battery fire extinguishing agent is simple and easy to operate, used components have high safety, and damage to environments and human bodies is not prone to being left; and according to the lithium-ion battery fire extinguishing agent, the dodecyl fluoride-2-methyl-3-pentanone and water vapor are gasified by absorbing heat, the temperature of ignition positions is lowered, the re-ignition probability of lithium battery fire disasters is reduced, flame can be effectively coved through cooperation with foam, the problem of contents flying out when a lithium battery burns is solved, the possibility of new ignition point generation is reduced, and the spread of the lithium battery fire disasters is inhibited.