The invention discloses an electric vehicle coupling heat management system with high safety, which mainly uses the combination of a control chip, a wire, a class I battery, a battery cell, a class IIbattery, a globe valve, a condenser, an air compressor, an evaporator, a heater and a battery radiator to form the electric vehicle coupling heat management system with high safety. The control chipis connected with the class I battery, the class II battery, the condenser, the air compressor, the evaporator and the battery radiator respectively through the wire; when the internal temperature ofthe class I battery is higher than 35 DEG C, the control chip transmits the internal current of the class I battery to the inside of the class II battery, so that the heat management system can quickly transfer and adjust the energy, so as to avoid the damage of the battery when the internal temperature is higher and the life is lower; by setting an aerogel and graphene heating film, the thermal diffusion can be restrained by the aerogel and graphene heating film when the battery cell is out of control.