The invention discloses a nano-structure graphite carbon material as well as a preparation method and application thereof. The method comprises the following steps: taking cheap plant materials and acarbon-containing compound as raw materials and sequentially performing treatment such as soaking, rolling, extrusion, carbonization, activation and graphitization to finally obtain the nano-structuregraphite carbon material. Nanometer holes naturally formed by a plant material compact layer are completely utilized, a filling agent is added, rolling and extrusion treatment are conducted, and theholes with the hole diameter being equal to or more than 100 nanometers are reduced, so that the nano-structure graphite carbon material has a three-dimensional porous structure; furthermore, the specific surface area is proper, material exchange and efficient circulation of an energy storage device are benefited, the capacity is increased, and charging speed and discharging speed are increased, so the nano-structure graphite carbon material is very suitable for preparation of an electrode of electricity storage devices.