The invention relates to a brazing and casting process of a metal ceramic composite lining board. The brazing filler metal adopted by the process comprises the following ingredients by weight percent: 10-70% of Cu powder, 20-70% of Ti powder and 5-20% of surface active elements. The process comprises the following steps of: adding 10-20% of ceramic particles serving as a wetting enhanced phase into the brazing filler metal to prepare a composite brazing filler metal, cleaning a metal layer and a ceramic layer by using an organic solvent cleaning agent, fixedly assembling the metal layer and the ceramic layer in a sequence of the ceramic layer, the composite brazing filler metal, the metal layer, the composite brazing filler metal, the ceramic layer, the composite brazing filler metal and the metal layer, placing the fixedly-assembled metal layer and ceramic layer in a vacuum brazing furnace for brazing, after brazing, placing a metal ceramic layer and a metal matrix into a casting die, pouring liquid steel and casting. The prepared metal ceramic composite lining board has the advantages of good toughness, high wear-resisting property and high corrosion-resisting property, and meanwhile, the metal ceramic layer occupies a small part of the lining board and is low in cost, thus improving the production efficiency, saving the production halt and change time and comprehensively increasing the economic benefit for the industries of cement, metallurgy, mine, electricity and the like.