The present invention discloses a duplex-phase golf club head titanium alloy, which contains 6.0-7.5 wt% of aluminum, 1.5-2.5 wt% of vanadium, 1.5-2.5 wt% of chromium, 0.1-0.5 wt% of iron, 1.5-2.5 wt%of tin, 1.5-2.5 wt% of zirconium, 0.1-0.5 wt% of silicon, and other trace elements inevitable in an alloy material manufacturing process and with the ratio by using titanium as a base material. According to the present invention, after the duplex-phase golf club head titanium alloy is subjected to 780-840 DEG C plastic processing and heat treatment, the alloy structure with the alpha phase and the beta phase can be obtained; and due to the combination of the multiple alloying elements, the subgrain and high-density differential arrangement structure is generated in the alloy matrix, and the trace amount of the fine omega-phase precipitate can be formed, such that the duplex-phase golf ball bar head titanium alloy can have the tensile strength of 1300-1450 MPa, have the yield strength of 1250-1400 MPa, and the elongation of 6-12% so as to improve the design space of the golf club head structure.