The invention relates to a concrete with anti-cracking, anti-seepage and high-durability effects and a preparation method thereof. The concrete is prepared from the following components of cement, flyash, silicon powder, coal gangue powder, boron nitride, phosphor residue powder, sand, crushed stone, high-strength polyvinyl alcohol fiber, a water reduction agent, a dispersing activator, a modified graphene oxide dispersion liquid and water. The concrete has the advantages that the heat conduction coefficient in the 1h age period is 2.9 to 3.7W / (m.K), the heat conduction coefficient in the 28-day age period is 3.5 to 4.7W / (m.K), the compressive strength is 67.6 to 98.3MPa, the break strength is 13.3 to 16.8MPa, the split strength is 9.3 to 9.8MPa, the tensile strength is 8.3 to 10.7MPa, and the tensile elastic modulus is 44.5 to 51.4GPa; the anti-water permeation property, anti-chlorine ion permeation property, anti-freezing and thawing property, and anti-carbonizing property can reachthe highest level; the working property is high, the volume stability is high, the durability is high, the toughness is high, the anti-cracking ability is high, and the anti-seepage ability is high.