The invention relates to a press roll for pressing a secondary battery electrode and a producing process thereof, belonging to the technical field of mechanical manufacture and electrochemical power sources. The producing process of the press roll used for pressing the secondary battery electrode comprises the following steps of: performing a molding process on raw materials, namely rare earth alloy containing carbon, molybdenum, chromium, nickel, tungsten, silicon, manganese and lanthanum series and ferrous electroslag remelting steel ingots; heating and then forging and pressing to form a press roll blank by using a hydraulic press; performing balling heat treatment, performing furnace cooling, then raising the temperature, performing homeothermy to constant temperature; and finally performing postprocessing. In the invention, an ultradeep quenching treatment method is adopted, the treatment depth ranges from 10mm to 15mm below the surface of the press roll, thereby the hardness of the press roll is increased, the strength is improved, and high-precision electrode pressing is ensured; and the press roll produced by using the method has the advantages of high hardness, high strength and good wear resistance, can be widely applied to various precision presses, saves use cost, improves product quality and increases production efficiency.