The invention discloses a preparation method of a furandicarboxylic acid
diamine polymer, which comprises the following steps of dissolving and mixing
diamine and furandicarboxylic acid, and reactingunder the protection of
inert gas to generate a precipitate until the precipitate is not increased any more, thereby obtaining a composite salt, adding composite salt into a reactor, introducing inertgas, continuously vacuumizing, under the
catalysis of a catalyst, firstly pre-polymerizing until the
viscosity of the whole
system is not increased any more, and then raising the temperature for polycondensation until the
viscosity of the whole
system is not increased any more, so as to obtain a furandicarboxylic acid
diamine oligomer, and under the protection of
inert gas, carrying out
solid-phase
polymerization on the obtained furandicarboxylic acid diamine
oligomer to obtain the furandicarboxylic acid diamine
polymer. According to the method, furandicarboxylic acid and diamine generate composite salt, a
polymer is obtained through prepolymerization and condensation
polymerization, and then the furandicarboxylic acid diamine polymer is obtained through
solid-phase
polymerization and purification. The test conditions are simple, no
solvent is used, and no organic waste liquid is generated in the preparation process.