The invention discloses a testing method of sodium-naphthalene solution active concentration. In the absence of air and water, hydrochloric ether is used as dechlorinating agent to act with sodium-naphthalene solution, reaction temperature is 40-70 DEG C, reaction time is 5-15 minutes, sodium chloride is generated, at pH 6-10, sodium chloride is generated with water extraction, extraction time is 1-5 minutes, titrate sodium chloride in water solution with silver nitrate titrating solution, sodium-naphthalene solution active concentration is calculated according the consumption of silver nitrate standard solution. The invention has advantages of scientific test principle, reasonable design method, simple acquired method, simple test operation, which can be completed within 10-15 minutes and fast analysis speed, the relative standard deviation is less than 2%, the test result has good reproduction quality, and the test method is effective and practical.