The invention relates to a method for producing
polymer grade 1-
butene from C4 catalyzed by high
sulfur in a
refinery, which is a purification method for C4 catalyzed by the high
sulfur that is the by-product of
refinery process in
petrochemical industry. The invention discloses that coarse desulfurization of the C4 catalyzed by a high
sulfur refinery is carried out in a de-C5
tower, and at least desulfurizing,
drying, organic sulfur removing and washing are carried out by a water
scrubber and a reactor, thereafter,
material flow enters the reactor and etherification is carried out for removing isobutene, as well as hydrogenation is added selectively and removing
diene. Then the
material flow is separated by a
distillation column, and adsorbed by a
molecular sieve in the reactor, so as to obtain the
polymer grade 1-
butene with the purity of the 1-
butene to be over 99 percent, wherein, the total
sulfur content is less than 2mg / m<3>. By adopting the invention, the mixed C4 with high sulfur is desulfurized at first until the
sulfur content is less than 10mg / m<3>, and then enters different reactors, and the catalyst activity is not affected, thus leading the 1-butene to achieve
polymer grade standard finally. The production technique of the invention is characterized by short process, easy operation, and the like, and has the advantages of environmental
sanitation, safe production and comparatively low cost.