The invention relates to a detection and early-warning method of an early-warning system based on abnormal gas detection in high-voltage chamber. The abnormal gas detection early-warning system is composed of a micro-processor, an I/O (Input/Output) interface, a liquid crystal display screen, a keyboard, an analog-digital converter, a sampling holder, a multipath channel switching switch, a current-to-voltage converter, an HCL gas sensor, an SO2 gas sensor, a CO gas sensor and an ozone gas sensor, wherein the I/O interface, the liquid crystal display screen, the keyboard and the analog-digital converter are connected with the micro-processor, and the sampling holder, the multipath channel switching switch, the current-to-voltage converter, the HCL gas sensor, the SO2 gas sensor, the CO gas sensor and the ozone gas sensor are sequentially connected with the analog-digital converter. The control program of the early-warning method adopts two timer interruptions, a main software program used for each branch control of the program and a timer interruption 0 used for data acquisition control. The early-warning system has the advantages that multipath signals are sequentially acquired through multi-channel switching, and analog quantity signals are converted into data signals identified by a computer and are compared with a preset range; and if the signals are beyond the range, the system can give an alarm to achieve the purpose of early warning; meanwhile, a large-screen human-machine interface human-machine interface is arranged, and user operation is convenient and flexible.