The invention relates to a selective separation
recovery technology of heavy
metal in
electroplating sludge containing
chromium. The selective separation
recovery technology of the heavy
metal in theelectroplating
sludge containing the
chromium specifically comprises the steps that (1) the
sludge containing the
chromium and
carbonate are subjected to mix
roasting under a certain temperature,
andiron sources are supplemented appropriately; (2)
hydrothermal reaction is carried out on a
solid obtained in the step (1) and an alkaline mineralizing agent; (3) after
solid-liquid separation is carried out on turbid liquid obtained in the step (2) by using magnetic force, a diluted acid solution (pH is 3.5-5.0) is added into the
solid for
calcium removal, and concentration and
crystallization arecarried out for recovering the chromium after liquid dezincification; and (4) after the
magnetic separation of the turbid liquid in the step (3) is carried out, mixed reaction is carried out on the solid and a concentrated acid solution (pH is 2-3.5); and after the
magnetic separation of the obtained turbid liquid is carried out, the solid is a
nickel ferrite product, and
copper is recovered in aliquid mode. According to the selective separation
recovery technology of the heavy
metal in the
electroplating sludge containing the chromium,
doping regulation and control of metal elements in thesludge in
spinel class materials (M (II) N (III) 2O4 (M=Ni, Cu, Zn, Ca; N=Cr, Fe, Al)) is realized through comprehensive regulation and control of the
roasting temperature and a hydrothermal mineralizing agent, so that the selective separation recovery technology of the heavy metal is realized. Meanwhile, after the sludge is subjected to a
roasting / hydrothermal combined technology, the solid has higher magnetic force, and the difficulty of solid-liquid separation in the technology is reduced.