The invention belongs to the field of two-dimensional material preparing, and particularly discloses a VDW dielectric material and a preparing method and application thereof. The method comprise the following steps that an inorganic molecular crystal serves as an evaporation source, a heat evaporation method is adopted, the inorganic molecular crystal is subjected to sublimation under the high vacuum, meanwhile, a perfect molecular structure of the crystal can be kept, evaporation is carried out, and a VDW film is obtained. Due to the fact that unsaturated chemical bonds do not exist in inorganic molecules, the VDW film surface has no suspension bonds, and preparing of the VDW dielectric material can be finished. The prepared VDW film can serve as a dielectric material of a two-dimensionalmaterial electronic device, the scattering source of carriers in a two-dimensional groove material can be obviously reduced, it is ensured that a two-dimensional material has the high migration rate,meanwhile, a preparing technology and a semiconductor preparing technology are compatible, and scale preparing and integrating are easy.