The invention belongs to the technical field of
pigment synthesis, discloses halogenated ornamental blue as well as a preparation method and application thereof, and breaks through a traditional amino modification-based derivation path of ornamental blue.
Halogen is introduced into a main molecular structure of ornamental blue, and 5, 5-dihydroxy ornamental blue reacts with a specific halogenating agent to prepare the blue-light-emitting material. During preparation, 5, 5-dihydroxy blue and a halogenating agent react for 1-2 hours at the temperature of 20-30 DEG C in solvents such as dioxane and
acetonitrile according to the
molar ratio of 1: 1-1: 3, and a product can be obtained through
ice water quenching, filtering, washing and
drying. The synthesis method is simple and convenient, and post-treatment is simple. The halogenated ornamental blue is excellent in
dyeing performance, the K / S value exceeds 10, the
dye uptake exceeds 91%, and the color fastness to sun, washing and wet
rubbing reaches level 5, which is obviously superior to that of lemon yellow and 5, 5-dihydroxy ornamental blue, so that the halogenated ornamental blue not only can be used for
dyeing, but also can be used as an intermediate for synthesis of other derivatives, and the family structure and the application scene of the ornamental blue are enriched.