The invention relates to a nanometer silicon dioxide hybrid vinyl phenyl silicon intermediate material and a preparing method and application thereof. Nanometer silicon dioxide particles are dispersed uniformly and stably, and the nanometer silicon dioxide hybrid vinyl phenyl silicon intermediate material has the advantages of resisting high temperature and corona and being high in activity, the temperature index measured according to a secant method is 200 DEG C-240 DEG C, measured corona resistant time is 18-36 h, vinyl active points carried by the intermediate material is in good compatibility with polyesterimide, heat-resistant polyester, hydrogen-containing silicone and modified epoxy, the intermediate material is particularly suitable for preparing high-temperature-resistant and corona-resistant solvent-free insulating paint, in the using process, volatile gas is avoided, and pollution to the atmosphere environment is avoided. The preparing method for the nanometer silicon dioxide hybrid vinyl phenyl silicon intermediate material is simple, the reaction temperature is low, viscosity of the product and the content of nanometer silicon dioxide are controlled by controlling the quantity of adopted catalysts, molecular weight modifiers and the reaction temperature, and therefore the applicability of the product is wider.