The invention discloses a
polyolefin-based high-barrier film with a renewable structure and a preparation method of the
polyolefin-based high-barrier film, and belongs to the technical field of
polymer processing. According to the method disclosed by the invention, a dispersed phase
polymer A in the
polyolefin film is subjected to in-situ deformation through a specific two-way stretching process to generate a huge amount of two-dimensional sheet structures, so that the
diffusion paths of small molecules in the film are increased, and the gas
permeability coefficient of the film can be reduced by 1-2 orders of magnitude. A two-dimensional filler and an in-situ formed two-dimensional
polymer A are bridged to form a barrier network, and the barrier network has a special effect of cooperatively blocking gas small molecules. According to the prepared high-barrier packaging material, a special
microstructure with a macroscopic single layer, a microcosmic multi-layer and multi-component structure is creatively obtained in situ, the structure endows the material with excellent
gas barrier performance, and the high-barrier packaging material can be obtained again through melt
processing of the preparation method disclosed by the invention after forming. The high-barrier packaging material is easy to recycle and has a very good application prospect.