The present application relates to gas detection analysis technical field, especially to a kind of three-
electrode oxygen probe's automatic calibration method.Content includes: construct closed calibration box, and the output
voltage of standard
oxygen concentration and the probe to be calibrated is synchronously collected;Based on standard
oxygen concentration variation, construct
atmosphere evolution state quantity, combine the output
voltage of the probe to be calibrated, calculate
electrode response trajectory quantity;
Atmosphere evolution state quantity and
electrode response trajectory quantity are fused, and relative response characteristic quantity is constructed, combined with the nonlinear response of the probe to be calibrated in different oxygen concentration range and
zero drift, dynamic calibration model is constructed, and the oxygen concentration output result after calibration is obtained, and the parameter in dynamic calibration model is iterated and updated, and calibration parameter is obtained.The three-electrode oxygen
probe calibration method does not consider gas dynamic
diffusion and probe
response delay, and lacks effective compensation for nonlinearity and
zero drift, which leads to insufficient detection accuracy.