The present invention relates to a
lithium-supplementing positive
electrode material and a preparation method and application thereof. The
lithium-supplementing positive
electrode material has a core-shell structure, including a
lithium-supplementing core, a first rigid
coating, an active material layer and a second rigid
coating arranged in sequence from the inside to the outside, wherein the first rigid
coating and the second rigid coating both contain
metal carbides and / or
metal nitrides. The present invention improves the structural strength of the lithium-supplementing particles while improving the
conductivity of the positive
electrode material by wrapping the lithium-supplementing particles inside the positive electrode active material and coating the rigid coating on the surface of the lithium-supplementing particles and the surface of the active material layer. This can not only avoid the influence of the structural collapse of the lithium-supplementing particles after lithium-supplementing on the stability of the battery, but also reduce the
contact resistance between the lithium-supplementing agent and the active material and between the positive electrode materials, and enhance the
conductivity of the positive electrode active material, so that the lithium-
ion battery containing the lithium-supplementing positive
electrode material has both
high energy density and excellent rate performance and cycle stability.