The invention discloses environment-friendly and non-irritant whiteboard marker ink for classrooms. The ink is prepared from raw materials as follows: brown ferrotitanium powder, black copper-chromiumpowder, fluorinated graphite, sepiolite powder, bamboo charcoal micropowder, polyvinylpyrrolidone, black cocoa powder, rhizoma curcumae longae, beetroot juice, hydroxypropyl guar gum, an ethanol water solution, 2-acrylamide-2-methylpropanesulfonic acid, 4-vinylpyridine, acrylic acid, sodium dodecyl sulfate, soda water, 3-chloropropyl alkoxy silane, chloroacetic acid, tetramethylethylenediamine and a stabilizer. The ink polymer raw materials form the ink, biological pigment can prevent the harm caused by eating by mistake, and the ink has good film forming property, uniform films and good stability and has the characteristics of that the ink is energy-saving, environmentally friendly, non-toxic, free of irritant odor and easy to write and erase, the production process is simple and low incost, the product has stable performance for a long time and the ink cannot penetrate into whiteboard surfaces to cause pollution after being used for a long time.