The utility model discloses a stack spraying clamp device with an improved structure. The stack spraying clamp device comprises a clamping bottom plate, a clamping cover plate, a locking bolt and a plurality of clamping middle plates, wherein the clamping bottom plate is provided with a bottom plate positioning convex column, the clamping cover plate is provided with a cover plate positioning convex column, and the clamping middle plates are provided with middle plate positioning convex columns; a bottom plate through hole is formed in the clamping bottom plate, a cover plate through hole is formed in the clamping cover plate, the locking bolt comprises a limiting blocking part, a straight rod part and an elastic inserting and buckling part, and an elastic piece is arranged at the position, above the limiting blocking part, of the lower end of the straight rod part; the clamping cover plate is provided with a cover plate profiling positioning pin, and each clamping middle plate is provided with a middle plate profiling positioning pin; the elastic inserting and buckling part comprises two elastic buckling arms, and an arc-shaped bent middle connecting part is arranged between the two elastic buckling arms. By means of the structural design, the clamp has the advantages of being novel in structural design, good in stability and reliability and high in clamping accuracy.