46results about How to "Good thermal and hydrothermal stability" patented technology

A molecular sieve containing composition, which can be applied in catalytic cracking reaction for producing more ethylene and propylene, and its preparation method. The composition contains a pentasil-type molecular sieve having a SiO2 / Al2O3 molar ratio of 15-60, prepared by activation and modification with phosphorus, alkaline earth metal and transition metal. The composition essentially includes 85 DIFFERENCE 98% wt of pentasil-type molecular sieve, 1 DIFFERENCE 10% wt of P2O5, 0.3 DIFFERENCE 5% wt of alkaline earth oxide, and 0.3 DIFFERENCE 5% wt of transition metal oxide. The molecular sieve structure and active centers have high thermal and hydrothermal stability. The salient feature of this composition is that when applied as an active component of cracking catalyst for catalytic pyrolysis process, the yield of ethylene is above 18% and the total yield of ethylene and propylene is more than 40%.

The present invention belongs to the field of fine chemical technology, and is especially the preparation process of double pore high silicon zeolite molecular sieve as one kind of composite molecular sieve. The present invention features that by using type-Y high silicon zeolite as silicon and aluminum source, and through dissolving the surface of the high silicon type-Y crystal grain, mixing with ammonia water solution of ammonium tetraethyl bromide, adding certain amount of silica gel via stirring, crystallizing at 140-170 deg.C for 5-10 days, washing, stoving and roasting to eliminate template agent, double pore high silicon zeolite molecular sieve with both type-Y and type-beta molecular sieve pore canals is obtained. The double pore high silicon zeolite molecular sieve has low synthesis cost and high hydrothermal stability, and may be used in petrochemical industry.

A catalyst for selective catalytic reduction of NOx having one or more transition metals selected from Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir, Pt, and mixtures thereof supported on a support, wherein the support has a molecular sieve having at least one intergrowth phase having at least two different small-pore, three-dimensional framework structures.

A catalyst for selective catalytic reduction of NOx having one or more transition metals selected from Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir, Pt, and mixtures thereof supported on a support, wherein the support has a molecular sieve having at least one intergrowth phase having at least two different small-pore, three-dimensional framework structures.

The invention discloses a ZSM-5-based hierarchical porous molecular sieve. The dimension of the ZSM-5-based hierarchical porous molecular sieve material prepared in the invention is 100nm-20[mu]m; when the dimension of the ZSM-5 molecular sieve is greater than 1[mu]m, the ZSM-5 molecular sieve has a cruciate flower morphology, every individual is formed by accumulating nanometer crystals, and a gap among the nanometer crystals forms a mesopore; or when the dimension of the ZSM-5 molecular sieve is not greater than 1mum, the ZSM-5 molecular sieve has a nanometer rod plug self-assembling morphology characteristic, and a gap among nanometer rods forms a mesopore. The ZSM-5-based hierarchical porous molecular sieve is prepared by adopting cheap raw materials through a one step method with tetrapropyl ammonium bromide as a template. The method has the advantages of low cost and simple operation, and the obtained hierarchical porous molecular sieve material has good physical and chemical properties and a catalysis characteristic, and is suitable for the industrial production.

The invention provides a method for preparing Beta molecular sieve. The whole or parts of the aluminum sources are provided with the natural minerals such as kaolin and bentonite as raw materials and organic ammonium template is added to carry out crystallization reaction under hydrothermal condition to gain the crystallization product containing Beta molecular sieve. The gained crystallization product can use different post-processing method to prepare modification Beta molecular sieve and can be used as active constituent or carrier of the catalyst. The Beta molecular sieve prepared by the method of the invention has higher heat and hydrothermal stability, solves the problem of difficult filtering of Beta molecular sieve preparation and post-processing and can increase the production efficiency. The invention extends the range of raw materials of the compound Beta molecular sieve, finds novel purpose for more natural minerals and further lowers the cost of preparing Beta molecular sieve.

The double microporous zeolite and its preparation process belongs to the field of fine chemical technology. The preparation process is one two step crystallizing process including the first step of synthesizing Beta, and the second step of preparing composite zeolite product in BEA / FAU structure with the Beta as material and through replenishing aluminum source, regulating basicity of the system, adding guiding agent, filtering, washing, drying and roasting. The composite zeolite product has strong acidity, and excellent heat and hydrothermal stability, and may be applied as catalyst, co-catalyst and adsorbent in petrochemical industry.

This invention relates to stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 μm. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more.

The invention relates to a beta / ZSM-5 compound borosilicate molecular sieve. Non-water chemical constitution expression of the molecular sieve is: xNa2O.B2O3.ySiO2, wherein, x is 0.03-2 and y is 10-400. The molecular sieve is prepared by adding beta borosilicate molecular sieve, which is taken as inoculating seed, to synthetic materials of the ZSM-5 compound borosilicate molecular sieve by hydrothermal crystallization; therefore, the molecular sieve has strong acidic property and high aromatization performance.

The invention relates to a beta molecular sieve of high-content Fe in a framework and a preparing method of the beta molecular sieve. Tetraethylammonium hydroxide serves as a template agent, a Fe- complex serves as a Fe source, and the Fe-beta zeolite molecular sieve of high-content Fe in the framework is synthesized through a one-step method. The synthesizing method is simple, the silica-alumina ratio can be adjusted, the mass fraction of Fe in the framework can reach 3-8%, and the synthesized Fe-beta zeolite molecular sieve is neat in structure, high in crystallinity and good in application prospect.

The invention relates to a preparation method and application of a normal hydrocarbon hydroisomerization catalyst. The preparation method comprises the following steps: mixing deionized water and a phosphorus source, adding an aluminum source, a silicon source and a microporous template agent, mixing evenly, then adding a mesoporous template agent, stirring to obtain sol, aging, adding a matrix, and conducting dynamic hydrothermal crystallization; washing, separating, drying and roasting the products to obtain a cascade hole SAPO-11 / gamma-Al2O3 composite; and impregnating a metal active component to the cascade hole SAPO11 / gamma Al2O3 composite material by an isopyknic impregnation method, and then airing at room temperature, drying and roasting to obtain the normal hydrocarbon hydroisomerization catalyst. The invention also provides the application of the catalyst prepared by the above method to a normal hydrocarbon isomerization reaction. The catalyst prepared by the preparation method provided by the invention has high normal hydrocarbon hydroisomerization conversion as well as excellent selectivity on double branch and multiple branch isomers.

The invention discloses a preparation method of composite zeolite with a core / shell structure, belonging to the fields of fine chemical engineering and inorganic materials. The preparation method is characterized by being a preparation method of composite zeolite taking high-silicon Y type zoelite as a core and taking nano-polycrystalline ZSM-5 zeolite as a shell. The method takes the high-silicon Y type zoelite as a raw material and obtains the product by one-step crystallization by using a conventional template. According to the preparation method, the difficulty that the conventional methods cannot synthesize the core / shell type composite zoelite which takes Y type zoelite as a core and takes ZSM-5 zeolite as a shell is solved. The shell layer is a nano-polycrystalline ZSM-5 zeolite layer, and from the shell to the core, the spreading course is unique, the spreading route is greatly shortened and a hierarchical pore structure among nanocrystals exists on the surface, so that the composite zeolite with the core / shell structure has potential application value in the aspects of catalytic cracking, hydrogen cracking and the like in the fine chemical engineering and the petrochemical engineering.

The invention discloses a preparing method of deep aluminium-stripping Y-zeolite, which comprises the following steps: adopting NH4NaY with the content of Na2O not more than 2.5w%; proceeding first water heat disposal; utilizing high-density H+ ammonium salt solution to exchange to strip aluminium; proceeding second water heat disposal; removing non-frame aluminium through acid solution; setting the disposing temperature of second water heat disposal higher than the first one; improving crystallinity and silicon-aluminium rate with abundant secondary hole.

The present application discloses a copper-containing molecular sieve Cu-CHA, a catalyst thereof and use thereof in the treatment of diesel vehicle exhaust gas, and belongs to the field of catalytic materials. The copper-containing molecular sieve Cu-CHA consists of zeolite having a CHA framework structure and containing silicon and aluminum elements as well as 1.65-3.05wt% of Cu; the Cu-CHA molecular sieve also comprises 0.5-1.5wt% of boron, and the Cu-CHA molecular sieve has an acid content of 0.25-0.98mmol / g. The Cu-CHA molecular sieve of the present application has an acid density as highas 0.25-0.98mol / g and a Cu content as low as 1.65-3.05wt%. As a catalyst for the selective catalytic reduction of ammonia, the Cu-CHA molecular sieve has excellent storage capacity for NH3 and good low-temperature activity, and the absence of CuOx species in the high-temperature section prevents the reduction of high-temperature activity due to non-selective oxidation of NH3. The Cu-CHA molecularsieve catalyst shows excellent catalytic activity in a wide temperature window, taking into account both low temperature and high temperature activities, and still shows good catalytic activity afterbeing subjected to hydrothermal aging treatment; and after being used in the treatment of diesel vehicle exhaust, the Cu-CHA molecular sieve catalyst has significant performance advantages.

The invention discloses a large block porous zeolite composed of nano-crystal grains and a preparation method thereof. The preparation method includes: taking a silicon source, an aluminum source, an alkali source, a quaternary ammonium salt template agent and sodium chloride as the raw materials to prepare gel, adding a crystal growth interference agent to prepare a blocky dry glue; subjecting the blocky dry glue and a gas template agent not in direct contact to vapor phase crystallization reaction so as to obtain the large block porous zeolite that is composed of 50-500nm primary zeolite crystal grains and has a 2-50nm intergranular mesoporous system. The porous zeolite synthesized by the method provided by the invention has improved diffusion rate and acid site accessibility, and has important application value in catalytic cracking, hydrocracking, adsorption separation and other aspects of fine chemical engineering and petrochemical engineering.

The invention relates to an aromatizatian catalytic material and a preparation method thereof. The aromatizatian catalytic material is a metal-modified molecular sieve and has the absolute chemical expression formula of (0-0.3) Na2O.(0.5-15) Al2O3.(0.5-15) MXOY.(70-99) SiO2 by the weight of oxide, wherein the M is modified metal loaded on the molecular sieve, x represents the atomic number of the M, the y represents a number required for meeting the oxidation state of the M, one part of the metal is partially acted with Al2O3 on the surface of the molecular sieve to form an MXOY-Al2O3 surface compound, the other part of the metal exists in a form of an independent phase of a metal oxide MXOY, and the proportion between one part of the metal and the other part of the metal is: MXOY-Al2O3 : MXOY is equal to (0.5-2) : 1. The provided aromatizatian catalytic material has the advantages of high degree of crystallization, large pore volume and specific surface area, high acid content and high cracking activity and aromatizatian selectivity.

The invention provides a pyrolysis catalyst and a preparation method thereof. The method comprises the following steps of: mixing molecular sieves, zirconium oxide powder and aluminium bonding agents, pulping, adding the zirconium oxide powder in pulp, pulping, regulating the pH value of the pulp with inorganic acid to be 2-5, and then spray drying, wherein the zirconium oxide powder is prepared by the following method comprising the steps of: mixing a zirconium salt water solution with ammonia water, ensuring that the quantity of the ammonia water is sufficient to regulate the pH value of a suspension to be 9-12, then ageing, filtering, washing, drying and baking at a temperature of 500-700DEG C. The catalyst prepared by the method has the advantages of good wear resistance, good crystallization degree and strong capability of resisting calcium pollution. When used for pyrolysis of calcium-containing hydrocarbon oil, the catalyst has high propylene yield.

The invention discloses a hydrocracking catalyst carrier and a preparation method of the hydrocracking catalyst carrier. The hydrocracking catalyst carrier is prepared by using modified Y zeolite, aluminum oxide and amorphous silicon-aluminum. The modified Y zeolite has the following physiochemical properties: the mole ratio of SiO2 to Al2O3 is 30-120; the lattice constant is 2.420-2.435nm; the relative crystallinity is more than or equal to 90%; the specific surface area is 750-850m<2> / g; the secondary pore with 1.7-10nm accounts for more than 50% of the total pore volume; the infrared acidity is 0.10-0.50mmol / g; the ion exchange capacity is less than or equal to 0.10%; and the water adsorption quantity is less than 5.0% in percentage by weight at 25 DEG C and P / P0 of 1.0. The preparation method of the catalyst carrier provided by the invention comprises the following steps: mechanically mixing the modified Y zeolite, aluminum oxide, amorphous silicon-aluminum and adhesive, grinding, extrusion-moulding, drying and calcining to obtain the catalyst carrier. The catalyst carrier prepared by using the modified (deeply dealuminated) Y zeolite as the acidic cracking component is suitable to be used as the hydrocracking catalyst for middle distillates oil.

The invention provides a zirconium-containing cracking catalyst and a preparation method thereof. The catalyst comprises 10 to 40 weight percent of aluminum binding agent, 0.5 to 50 weight percent of molecular screen, 0 to 60 weight percent of clay, and 3 to 25 weight percent of zirconia. The method is characterized in that in the catalyst preparing process, the zirconium is introduced at twice. The zirconium-containing catalyst prepared by the method has the advantages of good abrasion resistance, high crystallization degree, high calcium pollution resistance, application in cracking calcium-containing hydrocarbon oil and high propylene yield.

The invention provides a pyrolysis catalyst and a preparation method thereof. The method comprises the following steps of: mixing molecular sieves, zirconium oxide powder and aluminium bonding agents, pulping, adding the zirconium oxide powder in pulp, pulping, regulating the pH value of the pulp with inorganic acid to be 2-5, and then spray drying, wherein the zirconium oxide powder is prepared by the following method comprising the steps of: mixing a zirconium salt water solution with ammonia water, ensuring that the quantity of the ammonia water is sufficient to regulate the pH value of a suspension to be 9-12, then ageing, filtering, washing, drying and baking at a temperature of 500-700DEG C. The catalyst prepared by the method has the advantages of good wear resistance, good crystallization degree and strong capability of resisting calcium pollution. When used for pyrolysis of calcium-containing hydrocarbon oil, the catalyst has high propylene yield.

The invention provides a zirconium-containing cracking catalyst and a preparation method thereof. The catalyst comprises 10 to 40 weight percent of aluminum binding agent, 0.5 to 50 weight percent of molecular screen, 0 to 60 weight percent of clay, and 3 to 25 weight percent of zirconia. The method is characterized in that in the catalyst preparing process, the zirconium is introduced at twice. The zirconium-containing catalyst prepared by the method has the advantages of good abrasion resistance, high crystallization degree, high calcium pollution resistance, application in cracking calcium-containing hydrocarbon oil and high propylene yield.

The invention provides a catalytic cracking catalyst and a preparation method thereof. The preparation method comprises the following steps of: mixing and pulping zirconium oxide powder and roast kaolin slurry; mixing and pulping an aluminum adhesive; introducing zirconium oxide powder and a molecular sieve into the slurry, regulating the pH value of the slurry to be 2-5, and drying, wherein the zirconium oxide powder is prepared from an aqueous solution of zirconium salt and ammonia water, and the pH value of the obtained suspension is controlled to b3e 9-12; and aging, filtering, washing, drying and roasting at the temperature of between 500 and 700DEG C. The zirconium-containing catalyst prepared by the method has high wear resistance, crystallinity and resistance to contamination of metals such as iron and the like, is used for a catalytic thermal cracking process and ensures high yield of ethylene and propylene.

A modified Y zeolite and a preparation method thereof are disclosed; the modified Y zeolite comprises a IVB metal oxide and phosphor, the ratio of distorted four-coordinated framework aluminum to four-coordinated framework aluminum in the lattice structure of the modified Y zeolite is(0.2-0.8):1, and the ratio of zeolite surface IVB metal content to zeolite internal IVB metal content is not higher than 0.5. The preparation method comprises the following steps: acid treatment of zeolite materials, dehydration, immersion of a metal in an organic solvent, treatment of the zeolite immersed with the metal in the organic solvent, treatment of the modified Y zeolite by a phosphorus containing compound and calcination. The modified Y zeolite has high cracking activity, higher gasoline yield and lower coke yield for heavy oil cracking.

The invention discloses a catalytic cracking catalyst for producing low-carbon olefin. The catalyst consists of 0.5-15 parts by weight of particles A and 1 part by weight of particles B, wherein the particles A include 10-85 percent by weight of aluminum binder, 15-60 percent by weight of molecular sieve and 0-75 percent by weight of clay based on the total weight of the particles A; the molecular sieve is MFI zeolite or MFI zeolite and Y type zeolite; the clay is one or more of montmorillonoid, diatomite, halloysite, soapstone, sepiolite, attapulgite, hydrotalcite and bentonite; and the particles B include 20-80 percent by weight of rectorite and 20-80 percent by weight of silicon oxide binder in terms of silicon oxide based on the total weight of the particles B. The catalyst provided by the invention has high olefin yield and excellent wear resistance.

The invention relates to a beta / ZSM-5 compound borosilicate molecular sieve. Non-water chemical constitution expression of the molecular sieve is: xNa2O.B2O3.ySiO2, wherein, x is 0.03-2 and y is 10-400. The molecular sieve is prepared by adding beta borosilicate molecular sieve, which is taken as inoculating seed, to synthetic materials of the ZSM-5 compound borosilicate molecular sieve by hydrothermal crystallization; therefore, the molecular sieve has strong acidic property and high aromatization performance.

A kind of double microporous zeolite and preparation method thereof belong to the technical field of fine chemical industry, it is characterized in that adopting two-step crystallization method, the first step first synthesizes Beta, then with the synthetic Beta reaction mixture as the raw material of the second step synthesizing Y zeolite, The composite zeolite product with BEA / FAU structure is obtained by supplementing the aluminum source, adjusting the basicity of the system, adding the directing agent for synthesizing Y zeolite for reaction crystallization, filtering, washing, drying, and calcining. The method successfully solves the problems of pouring part of the clear liquid and difficult control of the amount of aluminum source and base added in the synthesis because the clear liquid contains components such as silicon, aluminum and alkali, and the product repeatability is difficult to control. The synthesized Beta / Y composite zeolite products can be used as various catalysts, catalyst assistants and adsorbents. After ion exchange, they have strong acidity and good thermal and hydrothermal stability. They can be used as various catalysts, catalyst assistants It is bound to have potential application value in catalytic cracking and hydrocracking of petrochemical industry.

The invention provides a method for preparing Beta molecular sieve. The whole or parts of the aluminum sources are provided with the natural minerals such as kaolin and bentonite as raw materials and organic ammonium template is added to carry out crystallization reaction under hydrothermal condition to gain the crystallization product containing Beta molecular sieve. The gained crystallization product can use different post-processing method to prepare modification Beta molecular sieve and can be used as active constituent or carrier of the catalyst. The Beta molecular sieve prepared by the method of the invention has higher heat and hydrothermal stability, solves the problem of difficult filtering of Beta molecular sieve preparation and post-processing and can increase the production efficiency. The invention extends the range of raw materials of the compound Beta molecular sieve, finds novel purpose for more natural minerals and further lowers the cost of preparing Beta molecular sieve.

The invention relates to the field of catalytic chemistry, and discloses a preparation method of 1, 1-dialkoxy alkane, the preparation method is as follows: in the presence of a catalyst, subjecting alcohol as shown in R1OH and aldehyde as shown in R2-CHO to a contact reaction, wherein the catalyst is a hydrogen type EWT structure molecular sieve, R1 is methyl, ethyl, propyl, butyl or pentyl, and R2 is hydrogen, methyl, ethyl, propyl or butyl. According to the method, a molecular sieve type catalyst with a hydrogen type EWT structure is adopted and has higher reaction activity and better acetal yield.