The invention discloses high-color-rendering composite fluorescent glass and a preparation method thereof. The high-color-rendering composite fluorescent glass comprises a PiG layer and a red fluorescent
powder layer. The preparation method of the high-color-rendering composite fluorescent glass comprises the following steps: weighing a certain amount of raw materials according to a low-melting-point glass formula, uniformly mixing, putting into a
crucible, melting for 0.1-4 hours, carrying out water
quenching on the
molten glass liquid,
drying,
grinding and sieving to obtain matrix glass
powder; the preparation method comprises the following steps: mixing matrix glass
powder and commercial green or yellow fluorescent powder according to a required
mass ratio, putting the mixture into a
crucible, melting for 0.1-4 hours, pouring a melt into a mold which is heated to a certain temperature, paving a layer of red fluorescent powder in the mold in advance, quickly covering the mold after the melt in the
crucible completely flows into the mold, continuously keeping the temperature for 0.1-1 hour, and cooling to
room temperature, thereby obtaining the red fluorescent powder. And naturally cooling to
room temperature, and carrying out annealing treatment to obtain the composite fluorescent
glass material. The preparation method provided by the invention is suitable for compounding matrix glass of different systems and various fluorescent powders, and is wide in application field and easy for large-scale production.