The invention provides an energy-saving and synergistic nano graphite lubricant additive and a preparation method thereof. The preparation method is characterized by comprising the following steps of: ball-milling graphite powder, deironing, separating and drying, and processing to obtain nano graphite powder; and mixing the nano graphite powder, gear oil, a dispersion stabilizer, basic oil and a solid lubricant to obtain the finished energy-saving and synergistic nano graphite lubricant additive. By the preparation method, the engine can save fuel oil by over 7 percent, reduce the lubricant oil consumption by 50 percent, prolong the oil change period by one time, reduce abrasion of machine parts and prolong the engine overhaul mileage by 50 percent; moreover, the abrasion is reduced, the abrasion rate of an engine cylinder is reduced by 25 to 36 percent, the engine air tightness is increased, the discharge of harmful gases in the tail gas is reduced, and dual benefit of saving the energy and protecting the environment can be gained.